Combined use of calcium nitrate, zeolite, and anion exchange resin for controlling phosphorus and nitrogen release from sediment and for overcoming disadvantage of calcium nitrate addition technology

Ca(NO₃)₂ addition has proved to have a high potential to immobilize internal phosphorus (P) in sediments; however, it cannot effectively stop the release of ammonium-nitrogen (NH₄⁺-N) from sediments into overlying waters (OL-waters). Additionally, the addition of Ca(NO₃)₂ alone has high risk of nitrate-nitrogen (NO₃⁻-N) releasing into OL-waters. To overcome the shortcoming of the Ca(NO₃)₂ addition method, we reported an integrated method, i.e., a combined method based on Ca(NO₃)₂ injection, zeolite capping, and anion exchange resin (AERN)–contained floating system suspending (Ca(NO₃)₂/zeolite/AERN). The effectiveness and mechanism of the Ca(NO₃)₂/zeolite/AERN method for simultaneously controlling the release of soluble reactive P (SRP) and NH₄⁺-N were investigated, and the NO₃⁻-N releasing risk of this method was evaluated. It was found that the joint use of Ca(NO₃)₂ injection, zeolite capping, and AERN-contained floating system suspending not only could effectively suppress the release of SRP and NH₄⁺-N from sediments into OL-waters simultaneously, but also had much less risk of NO₃⁻-N releasing into OL-waters as compared to the single Ca(NO₃)₂ injection method and the combined Ca(NO₃)₂/zeolite method. The inhibition of the reductive dissolution of the P-bound Fe(III) oxides/hydroxides by the presence of nitrate and the adsorption of ammonium on the zeolite played very important roles in the interception of SRP and NH₄⁺-N releasing into OL-waters by the Ca(NO₃)₂/zeolite/AERN method. After the sediment remediation using the Ca(NO₃)₂/zeolite/AERN approach, the increase in the content of residual P in the sediment layer of 0–50 mm, the decrease of mobile P in the sediment layer of 0–10 mm, and the increased NH₄⁺-N adsorption capacity for the sediment layer of 0–10 mm would be conductive to the interception of SRP and NH₄⁺-N liberation in the long run. Results of this research suggest a promising application potential of the Ca(NO₃)₂/zeolite/AERN method in the simultaneous control of the release of SRP and NH₄⁺-N from sediments.