Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C₅R₅)RuCl(PTA)₂] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane)
2003
Akbayeva, Dina N. | Gonsalvi, Luca | Oberhauser, Werner | Peruzzini, Maurizio | Vizza, Francesco | Brüggeller, Peter | Romerosa, Antonio | Sava, Gianni | Bergamo, Alberta
The new water soluble ruthenium complexes [(C₅R₅)RuCl(PTA)₂] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane) were synthesised and characterised. Their evaluation as regioselective catalysts for hydrogenation of unsaturated ketones in aqueous biphasic conditions and as cytotoxic agents towards the TS/A adenocarcinoma cell line is briefly presented.
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