On the sulfimidation of benzo[b]thiophene
2003
Archibald, Stephen J. | Boa, Andrew N. | Peša, Nela
Benzo[b]thiophene and chloramine-T react in the presence of catalytic amounts of [Cu(NCMe)₄]BF₄ to yield a novel dihydrobenzothiazine arising from a ring-expansion; if the reaction is conducted in the absence of the copper(i) catalyst no reaction takes place, but the expected sulfimide can be made using [(N-tosylimino)iodo]benzene, PhINTs.
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