Remarkable thermodynamic stability toward hydrolysis of tripodal titanium alkoxides
2004
Ugrinova, Vesela | Ellis, Gregory A. | Brown, Seth N.
The monomeric titanium(iv) hydroxide complex, LTi(OH) (LH₃ = tris(2-hydroxy-3,5-di-tert-butylbenzyl)amine), which is sterically inhibited from condensation to a μ-oxo dimer, cannot be prepared by hydrolysis of the alkoxide, with Kₑq = 0.012 for hydrolysis of the titanium methoxide in THF.
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