PINO/NHPI-mediated selective oxidation of cycloalkenes to cycloalkenones via a photo-electrochemical method
2019
Tateno, Hiroyuki | Miseki, Yugo | Sayama, Kazuhiro
The selective photo-electrochemical oxidation of cyclohexene to 2-cyclohexene-1-one was successfully performed with excellent Faraday efficiency (>99%) via indirect oxidation with a PINO/NHPI mediator and O₂ on a BiVO₄/WO₃ photoanode under low applied bias.
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