SO2-tolerant and H2O-promoting Pt/C catalysts for efficient NO removal via fixed-bed H2-SCR

Tu, Baosheng; Shi, Nian; Sun, Wei; Cao, Limei; Yang, Ji

SO2-tolerant and H2O-promoting Pt/C catalysts for efficient NO removal via fixed-bed H2-SCR

2017

Tu, Baosheng | Shi, Nian | Sun, Wei | Cao, Limei | Yang, Ji

In this paper, Pt supports on carbon black powder (Vulcan XC-72) were synthesized via a hydrothermal method for selective catalytic reduction (SCR) of NO with H₂ in the presence of 2 vol% O₂ over a wide temperature of 20–300 °C. The results showed that the 3 and 5 wt% Pt/C catalysts resulted in high NO conversion (>90 %) over a temperature range of 120 to 300 °C, and the maximum NO conversion of 98.6 % was achieved over 5 wt% Pt/C at 120 °C. Meanwhile, the influence of SO₂ and H₂O on the catalyst performance of 3 wt% Pt/C was investigated. The catalysts exhibited good SO₂ poisoning resistance when the SO₂ concentration was lower than 260 ppm. Moreover, a positive effect on NO conversion was detected with the addition of 3 and 5 vol% H₂O in the feed gas stream. Graphical abstract TEM image and good NO conversion performance of the Pt/C catalysts

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