Biosorption performance of date palm empty fruit bunch wastes for toxic hexavalent chromium removal

Biosorption ability of date palm empty fruit bunch (DPEFB) was examined for the removal of toxic hexavalent chromium (Cr⁶⁺) ions from synthetic wastewater. The pretreated DPEFB biosorbent was studied for its morphology and surface chemistry through Scanning electron microscopy, Energy dispersive elemental analysis and Fourier transform infrared spectroscopy. Effect of biosorption parameters such as pH, biosorbent dosage, contact time, temperature, initial feed concentration and agitation speed on the Cr⁶⁺ ions removal efficiency by DPEFB was critically evaluated. The isoelectric point for the DPEFB sorbent was observed at pH 2, above which it was dehydronated to capture the positively charged Cr⁶⁺ ions. Batch biosorption studies showed that an optimal chromium removal efficiency of 58.02% was recorded by the DPEFB biosorbent for pH 2, dosage 0.3 g, 100 rpm agitation speed, 120 min contact time, 50 mg/L initial feed concentration and 30 °C operational temperature. Thermodynamic analysis showed that the binding of Cr⁶⁺ ions on DPEFB surface was exothermic, stable and favorable at room temperature. Equilibrium behavior of chromium binding on DPEFB was more aligned to Temkin isotherm (R² = 0.9852) highlighting the indirect interactions between Cr⁶⁺ ions and the biosorbent. Kinetic modeling revealed that the biosorption of Cr⁶⁺ ions by DPEFB obeyed pseudo-second order model than the pseudo-first order and intra-particle diffusion models. Reusability studies of the DPEFB sorbent showed that NaNO₃ was an effective regenerant and the biosorbent can be efficiently reused up to three successive biosorption-desorption cycles for chromium removal. In summary, the results clearly showed that the DPEFB biowaste seems to be an efficient, economic and eco-friendly biosorbent for sustainable removal of toxic hexavalent chromium ions from domestic and industrial wastewater streams.