Photocatalytic degradation of amoxicillin from aqueous solutions by titanium dioxide nanoparticles loaded on graphene oxide

Balarak, Davoud; Mengelizadeh, Nezamaddin; Rajiv, Periakaruppan; Chandrika, Kethineni

Photocatalytic degradation of amoxicillin from aqueous solutions by titanium dioxide nanoparticles loaded on graphene oxide

2021

Balarak, Davoud | Mengelizadeh, Nezamaddin | Rajiv, Periakaruppan | Chandrika, Kethineni

The photocatalytic degradation of amoxicillin (AMX) by titanium dioxide nanoparticles loaded on graphene oxide (GO/TiO₂) was evaluated under UV light. Experimental results showed that key parameters such as initial pH, GO/TiO₂ dosage, UV intensity, and initial AMX concentration had a significant effect on AMX degradation. Compared to the photolysis and adsorption processes, the AMX degradation efficiency was obtained to be more than 99% at conditions including pH of 6, the GO/TiO₂ dosage of 0.4 g/L, the AMX concentration of 50 mg/L, and the intensity of 36 W. Trapping tests showed that all three hydroxyl radical (OH•), superoxide radical (O₂•⁻), and hole (h⁺) were produced in the photocatalytic process; however, h⁺ plays a major role in AMX degradation. Under UV irradiation, GO/TiO₂ showed excellent stability and recyclability for 4 consecutive reaction cycles. The analysis of total organic carbon (TOC) suggested that AMX could be well degraded into CO₂ and H₂O. The formation of NH₄⁺, NO₃⁻, and SO₄²⁻ as a result of AMX degradation confirmed the good mineralization of AMX in the GO/TiO₂/UV process. The toxicity of the inlet and outlet samples of the process has been investigated by cultivation of Escherichia coli and Streptococcus faecalis, and the results showed that the condition is suitable for the growth of organisms. The photocatalytic degradation mechanism was proposed based on trapping and comparative tests. Based on the results, the GO/TiO₂/UV process can be considered as a promising technique for AMX degradation due to photocatalyst stability, high mineralization efficiency, and effluent low toxicity.

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