Terrestrial solar radiation driven photodecomposition of ciprofloxacin in clinical wastewater applying mesostructured iron(III) oxide
2021
Wagner, Daniel R. | Ament, Kevin | Mayr, Lina | Martin, Thomas | Bloesser, André | Schmalz, Holger | Marschall, Roland | Wagner, Friedrich E. | Breu, Josef
Cationic cylindrical polymer brushes based on polybutadiene-block-poly(2-vinylpyridine) were applied as structure-directing agent for mesostructuring Fe₂O₃ nanoparticles into nanotubes. After temperature-controlled template removal, the obtained non-woven catalysts were tested for the photodegradation of ciprofloxacin under terrestrial solar radiation. At a slightly basic pH value, as typically encountered in clinical wastewaters, the mesostructured Fe₂O₃ shows a 4.5 times faster degradation of ciprofloxacin than commercial Aeroxide® TiO₂ P25. Even wide-bandgap ZnO, mesostructured in the same way, is 1.6 times slower. Moreover, the non-woven-like structure of the catalyst allows for easy recovery of the catalyst and operation in a continuous flow reactor. Graphical abstract
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