Study of the Photocatalytic Activity Using Silica-Based Materials Doped with Silver Nanoparticles for Degradation of Rhodamine B Dye
2020
Nascimento Ribas, Lázaro | de Sousa Bulhões, Luis Otávio | da Silva, William Leonardo
Rhodamine B (RhB) is a cationic organic dye widely used industrially, mainly in the textile and food industries. Then, the work aims to study on the photocatalytic degradation of RhB dye, under UV and visible radiation, using photocatalyst silica-based materials synthesized by sol-gel route with different solvents (ethanol and n-propanol) and catalysts (C₁₂H₂₇N, HNO₃, NH₄OH, and NaOH) to the hydrolysis and condensation of tetraorthosilicate (TEOS). In addition, the effect of doping with silver nanoparticles (AgNPs) was evaluated on the photocatalytic activity. The samples were characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), N₂ porosimetry, zeta potential measurements (ZP), and Fourier transform infrared spectroscopy (FTIR). To evaluate the photocatalytic activity, photocatalytic tests were carried out in a stirred batch reactor, with the photocatalyst in suspension, under ultraviolet and visible radiation, and the target molecule chosen was the Rhodamine B dye (RhB). The photocatalyst Si–HNO₃–AgNPs showed the best photocatalytic activity with a degradation of the RhB dye of 90.16% (k = 0.0198 min⁻¹, under ultraviolet radiation) and 82.79% (k = 0.0148 min⁻¹, under visible radiation), after 120 min of reaction; while under the same conditions, the commercial catalyst TiO₂ (P25) showed a degradation of 50.02% and 42.14%, respectively.
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