Overriding ortho selectivity by template assisted meta-C–H activation of benzophenones
2020
Casali, Emanuele | Kalra, Prakriti | Brochetta, Massimo | Borsari, Tania | Gandini, Andrea | Patra, Tuhin | Zanoni, Giuseppe | Maiti, Debabrata
An orthogonal selectivity for distal meta-C–H activation of benzophenone is acheived by overriding the inherent proximal ortho-selectivity through a template assisted metalation approach. This strategy has been successfully utilized in Pd-catalyzed regioselective C–C and C–Si bond formation.
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