Nickel-catalyzed borrowing hydrogen annulations: access to diversified N-heterocycles
2019
YangThese authors contributed equally., Peng | Zhang, Caili | Gao, Wen-Chao | Ma, You | Wang, Xiuhua | Zhang, Li | Yue, Jieyu | Tang, Bo
Herein, we report an efficient nickel-catalyzed direct cyclization of amines with alcohols for the synthesis of various nitrogen containing heterocycles. These processes employ the sustainable “borrowing hydrogen” strategy and have many advantages, such as earth-abundant metal catalysts, easily available starting materials, wide synthetic versatility and harmless waste emission.
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