Ag(I)-Promoted Dehydroxylation and Site-Selective 1,7-Disulfonylation of Diaryl(1H-indol-2-yl)methanols
2018
Zhou, Yu | Cao, Wen-Bin | Zhang, Ling-Ling | Xu, Xiao-Ping | Ji, Shun-Jun
A novel dehydroxylation and site-selective 1,7-disulfonylation reaction of diaryl(1H-indol-2-yl)methanols with sodium sulfinates was described. The protocol provided an efficient strategy for the synthesis of disulfonylated 2-(diarylmethyl)indoles by exploring a range of substrates. The mechanistic studies revealed that silver nitrate served as both a Lewis acid and an oxidant for the sequential 1,7-disulfonylation process leading to the formation of final products.
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