Buchwald–Hartwig reactions in water using surfactants
2014
Salomé, Christophe | Wagner, Patrick | Bollenbach, Maud | Bihel, Frédéric | Bourguignon, Jean-Jacques | Schmitt, Martine
Examination of the scope and limitation of the Buchwald–Hartwig cross-coupling reaction in micellar medium is reported. An array of aryl or heteroaryl halides were coupled to diverse nitrogen coupling partners using a combination of [(allyl)PdCl]2 and cBRIDP to afford the corresponding products in moderate to excellent yields. 30 examples are reported, including polar solid and fairly water-soluble organic substrates/reagents.
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