The impact of material design on the photocatalytic removal efficiency and toxicity of two textile dyes
2022
Cherif, Sonia | Djelal, Hayet | Firmin, Stephane | Bonnet, Pierre | Frezet, Lawrence | Kane, Abdoulaye | Amine Assadi, Aymen | Trari, Mohamed | Yazid, Hynda
This study deals with the toxicity of the treated solutions of two types of dyes, namely, the anthraquinonic Reactive Bleu 19 dye (RB19) and the bi-azoic Direct Red 227 dye (DR227), which are treated in single and binary mixture systems. The target molecules were removed by the photocatalysis process using ZnO as a catalyst, which was calcined at two temperatures 250 and 420 °C (ZnO₂₅₀ and ZnO₄₂₀) prepared in the lab by the one-step calcination method. XRD, TEM, EDX, XPS, FT-IR, BET, RAMAN, and EPR analyses were carried out to characterize the catalyst material. While the phytotoxicity was being conducted using watercress seeds, the cytotoxicity took place using a cell line (raw) and an intestinal cell (caco-2). The XRD analysis showed the partial calcination of ZnO₂₅₀ and the presence of anhydrous zinc acetate along with the ZnO nanoparticles (NPs). This result was not observed for ZnO₄₂₀. Despite the complete discoloration (100%) of all the final solutions, ZnO₂₅₀ exhibited a high cytotoxicity and phytotoxicity against the RB19 dye after the photocatalytic treatment; however, it was not the case of ZnO₄₂₀ which was selected as an eco-friendly photocatalyst for the degradation of organic dyes based on the results of removal efficiency, cytotoxicity, and phytotoxicity.
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