Determination of halosulfuron-methyl herbicide in sugarcane juice and tomato by capillary electrophoresis–tandem mass spectrometry
2015
Daniel, Daniela | dos Santos, Vagner Bezerra | Vidal, Denis Tadeu Rajh | do Lago, Claudimir Lucio
A capillary electrophoresis–tandem mass spectrometry (CE–MS/MS) method for the determination of halosulfuron-methyl (HSU) residue in samples of sugarcane juice and tomato is introduced and validated. The samples were submitted to a QuEChERS extraction procedure followed by electrophoretic separation in NH4HCO3 electrolyte (adjusted to pH 8.5) and detection by electrospray-tandem mass spectrometry. The total HSU migration took place in less than 3.5min, and the detection was accomplished by monitoring three fragmentation processes of this anion: m/z 435–182, 139, and 83. The R2 values for concentrations up to 100ppb (μgkg−1) were, respectively, 0.992, 0.992, and 0.978. Recovery values for samples spiked at three concentration levels (10, 20 and 50ppb) were in the range of 96–104% with standard deviation not greater than 5.0%. The limit of detection for HSU in sugarcane juice and tomato was 2ppb for both samples.
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