Enantioselective iridium-catalyzed hydrogenation of β,β-disubstituted nitroalkenes
2016
Yu, Yan-Bo | Cheng, Lei | Li, Yi-Pan | Fu, Yue | Zhu, Shou-Fei | Zhou, Qi-Lin
An iridium complex with a newly prepared chiral spiro amino-phosphine ligand efficiently catalyzed the hydrogenation of both β-aryl-β-methyl-nitroalkenes and β-alkyl-β-methyl-nitroalkenes to the corresponding saturated nitroalkanes, which represents the first report of a chiral catalyst that exhibits high enantioselectivity for the challenging hydrogenation of β,β-dialkyl-nitroalkenes.
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