CuO-ZnO-CdWO4: a sustainable and environmentally benign photocatalytic system for water cleansing
2021
Fatima, Bushra | Siddiqui, Sharf Ilahi | Ahmad, Rabia | Linh, Nguyen Thi Thuy | Thai, Van Nam
Currently, there is a major problem of water contaminations, especially of dyes, all over the world. A new technique is being developed daily for the treatment of contaminated water. In many ways, a photocatalytic degradation of a dye by a mixed metal oxide photocatalyst is counted as the best technique for water treatment. This paper also addresses the preparation and photocatalytic application of newly developed mixed metal oxide nanocomposite, CuO-ZnO-CdWO₄. A novel mixed metal oxide CuO-ZnO-CdWO₄ nanocomposite has been synthesized by a green route using Brassica Rapa leaves extract. The application of CuO-ZnO-CdWO₄ as a photocatalyst in wastewater treatment has been thoroughly discussed. Several spectroscopic and microscopic techniques were used to characterize the prepared nanocomposite. The photocatalytic activity of CuO-ZnO-CdWO₄ nanocomposite with a band gap of 3.13 eV was observed under the artificial visible light and sunlight for the degradation of Congo red dye. The results under sunlight show the 1.45 times greater removal efficiency than under the artificial visible light. Pseudo-first-order, diffusion, and Singh kinetics models were used to describe the kinetics of dye degradation. Pseudo-first-order model was found to be best fitted model for present study. The performance of CuO-ZnO-CdWO₄ was estimated by significant parameters such as quantum yield, figure of merit, turnover number, and mean turnover frequency. The value these parameters were calculated as 1.70 × 10⁻⁸ molecules photon⁻¹, 1.77 × 10⁻⁴, 2.98 × 10⁸ s⁻¹, and 3.31 × 10⁻⁴ s⁻¹, respectively. These parameters revealed high potential of CuO-ZnO-CdWO₄ for Congo red dye degradation.
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