Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2
2015
Shen, Duyi | Miao, Chengxia | Xu, Daqian | Xia, Chungu | Sun, Wei
The manganese complex Mn(S-PMB)(CF₃SO₃)₂ was proven to be highly efficient in the catalytic oxidation of several benzylic and aliphatic secondary alcohols with H₂O₂ as the oxidant and acetic acid as the additive. A maximum turnover number of 4700 was achieved in the alcohol oxidation. In addition, the Hammett analysis unveiled the electrophilic nature of this manganese catalyst with N₄ ligand.
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