Iron isotope of suspended particulate matter in Zhujiang River, Southwest China: Characteristics, sources, and environmental implications

Understanding the environmental iron cycle influenced by natural and anthropogenic processes is significant to obtain the key information on earth-surface evolution. Iron isotope compositions and elemental compositions of the suspended particulate matter (SPM) in Zhujiang River were investigated to provide key insights for the earth-surface iron cycle. The δ⁵⁶Fe values of SPM display the range from −0.05‰ to 0.34‰ (averaged 0.19‰) while the iron contents range from 0.73 wt% to 7.63 wt% (averaged 4.15 wt%). The Chemical Index of Alteration (CIA) shows that the main weathering type of SPM is intermediate weathering (mean CIA value: 79.12). While the main chemical weathering types are similar, the δ⁵⁶Fe values vary dramatically, indicating that chemical weathering is not the governing factor of δ⁵⁶Fe values of SPM. Furthermore, evidence from the enrichment factors (EF, 0.78 to 1.29) of iron and Zinc isotopes reveals that the iron input from anthropogenic activities is quite limited. The significant correlation between (Fe/Ca)SPM and (Na/Ca)SPM, (Mg/Ca)SPM, (Al/Ca)SPM and (K/Ca)SPM (0.73 < r < 0.99, p < 0.01, n = 22) and the A–CN–K diagram could confirm that clay minerals (especially smectite and illite) are important components of SPM. Meanwhile, the higher enrichment rates of La, Pr and Nd with the increasing iron contents denote heavy minerals (mainly Fe oxides/oxy-hydroxides) are also important compositions of SPM. Based on the isotopic mass balance, it shows that the iron flux of SPM to the oceans during the wet season would reduce the δ⁵⁶Fe values of the bulk ocean by 0.3%. The present study reports the iron isotope and elemental compositions of Zhujiang SPM and identifies its influencing factors (weathering, anthropogenic inputs, and minerals effect), and also provides a quantitative reference for the intriguing question on the distinct δ⁵⁶Fe values of oceans, which is beneficial for understanding iron cycle in earth-surface system.