Grafted Copolymerization Modification of Hemicellulose Directly in the Alkaline Peroxide Mechanical Pulping (APMP) Effluent and Its Surface Sizing Effects on Corrugated Paper

Dong, Liying; Hu, Huiren; Yang, Shuo; Cheng, Fei

Grafted Copolymerization Modification of Hemicellulose Directly in the Alkaline Peroxide Mechanical Pulping (APMP) Effluent and Its Surface Sizing Effects on Corrugated Paper

2014

Dong, Liying | Hu, Huiren | Yang, Shuo | Cheng, Fei

In this work, the graft copolymerization of acrylamide (AM) and methacryloyloxy ethyl trimethyl ammonium chloride (DMC) with the hemicellulose in the alkaline peroxide mechanical pulping (APMP) effluent was investigated using the Fenton agent (FeSO₄/H₂O₂) as an initiator. The effects of the reaction conditions on the characteristics of the graft copolymers were studied. On the basis of the graft copolymer characterization, the optimum conditions were as follows: total active ingredient concentration 31%, reactive temperature 50 °C, amount of the initiator 0.4%, ratio of H₂O₂ to FeSO₄ 1:1, molar ratio of DMC to AM 1.5:20 and optimum percentages of C, G, GE, and viscosity are 65%, 246%, 98%, and 5020 cP, respectively. Structure elucidation of the graft copolymer was obtained by ¹H NMR spectroscopy and FT-IR. Gel-permeation chromatography (GPC) was employed to determine the molecular mass and molecular mass distribution of hemicellulose and graft copolymer. The thermal degradation properties of hemicellulose and the graft copolymers were measured by thermo gravimetric analysis (TGA). The graft copolymer was subsequently used as a corrugated paper surface sizing agent, which can significantly improve the physical strength and water resistance of corrugated paper.

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