Development of plastic disks containing flame retardants for elucidating changes in their concentrations due to simulated weathering and the application of these disks to weathering tests

Hanari, Nobuyasu; Otake, Takamitsu; Itoh, Nobuyasu; Wada, Ayaka; Ohata, Masaki

Development of plastic disks containing flame retardants for elucidating changes in their concentrations due to simulated weathering and the application of these disks to weathering tests

2017

Hanari, Nobuyasu | Otake, Takamitsu | Itoh, Nobuyasu | Wada, Ayaka | Ohata, Masaki

Flame retardants (FRs) are useful because they can prevent combustion and delay the spread of fire after the ignition on commercial products containing plastics. However, such commercial products could be a primary source of environmental contamination with FRs. Plastic disks containing FRs were prepared to elucidate changes in the concentrations of the FRs after weathering tests. Acrylonitrile-butadiene-styrene (ABS) and polycarbonate (PC) resin were separately kneaded with a combination of three organic FRs [Dechlorane plus (DP), tetrabromobisphenol A (TBBPA), and triphenyl phosphate (TPhP)] and one inorganic FR [antimony trioxide (Sb₂O₃)]. The concentrations of TBBPA/TPhP and DP/Sb₂O₃ in the final preparations were respectively 1000 and 500 mg/kg in compliance with the RoHS directive on organobromine FR. The concentrations of elements in the final preparations were 300 mg/kg for chlorine, 600 mg/kg for bromine, 100 mg/kg for phosphorus, and 400 mg/kg for antimony, respectively. The analytical concentrations (three FRs and four elements) were consistent with the expected concentrations (maximum difference −9.5% in the PC disks). The FRs and elements in the disks were sufficiently homogenous (maximum inhomogeneity 4.3% in the PC disks). The prepared disks were subjected to weathering tests; the concentrations of TBBPA in the disks decreased significantly (30 to 40%) whereas the concentrations of the elements did not change under the condition of this study. On the other hand, there were no drastic differences on relationships of FRs and elements such as DP/chlorine and TPhP/phosphorus.

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