Remote radical halogenation of aminoquinolines with aqueous hydrogen halide (HX) and oxone
2018
Qiao, Li | Cao, Xianting | Chai, Kejie | Shen, Jiabin | Xu, Jun | Zhang, Pengfei
Simple and halide-atom economical HX reagents (X = Cl, Br and I) were applied to the remote CH bond halogenation reaction of 8-aminoquinoline amides. This strategy features a broad substrate scope and good functional group tolerance. A series of C5-halogenated 8-aminoquinolines were obtained in moderate to good yields under mild conditions.
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