Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp³–H for pyrrole synthesis
2013
Meng, Lingkui | Wu, Kun | Liu, Chao | Lei, Aiwen
The first palladium-catalysed aerobic oxidative intramolecular alkenylation of Csp³–H bonds was described. The reaction conditions were mild and molecular oxygen was used as the terminal oxidant. Kinetic studies showed that the Csp³–H metallation step was a slow step.
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