Copper-Catalyzed Direct Arylation of Cyclic Enamides Using Diaryliodonium Salts
2013
Gigant, Nicolas | Chausset-Boissarie, Laëtitia | Belhomme, Marie-Charlotte | Poisson, Thomas | Pannecoucke, Xavier | Gillaizeau, Isabelle
A convenient method for the copper(II)-catalyzed direct arylation of cyclic and nonaromatic enamides using diaryliodonium salts has been developed. The reaction demonstrates large functional group tolerance, good yields, and total regioselectivity with a C(3)-functionalization. The synthetic potential of this coupling was explored by using a range of readily accessible diaryliodonium salts and enamides.
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