Levels and spatial distribution of perfluoroalkyl substances in China Liaodong Bay basin with concentrated fluorine industry parks

Chen, Hong; Zhang, Can; Han, Jianbo; Sun, Ruijun; Kong, Xiangyun; Wang, Xiaomeng; He, Xin

Levels and spatial distribution of perfluoroalkyl substances in China Liaodong Bay basin with concentrated fluorine industry parks

2015

Eighteen different perfluoroalkyl substances (PFASs) were investigated in 35 river water samples and 34 sediment samples collected from rivers in the Liaodong Bay basin containing two fluorine industry parks. Perfluorooctanoate (PFOA) and perfluorooctane sulfonate (PFOS) were the predominant PFASs in freshwater, with median concentrations of 26.5ng/L and 1.87ng/L, respectively. However, perfluorobutane sulfonate (PFBS) had the highest maximum concentration (up to 124.1ng/L, approximately two orders of magnitude higher) in water at a site which is the nearest to the industrial source of PFASs. Total PFASs in water at this site were also the highest. In contrast, PFOA and perfluorooctadecanoate (PFOcDA) were the most abundant PFASs in sediment, with median concentrations of 1.19ng/g and 0.35ng/g, respectively. Total PFAS concentrations in sediment from the site near to the industrial park were significantly higher than the other rivers. Mass loading of total PFASs from the rivers flowing into Liaodong Bay was estimated to be 506kg/year.

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