Copper-Catalyzed N-Arylation of Nitroenamines with Diaryliodonium Salts
2017
Aradi, Klára | Mészáros, Ádám | Tóth, Balázs L. | Vincze, Zoltán | Novák, Zoltán
A novel synthetic methodology was developed for the N-arylation of nitroenamine derivatives utilizing diaryliodonium triflates and copper(I) chloride as a catalyst. The procedure enables the easy aryl transfer from the hypervalent species under mild catalytic conditions with unusual heteroatom preference and high efficiency.
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