Visible light photoredox-catalysed intermolecular radical addition of α-halo amides to olefins
2014
Nakajima, Masaki | Lefebvre, Quentin | Rueping, Magnus
We present α-chloro amides as a new class of α-acetyl radical precursors, which undergo a tin-free, photoredox-catalysed intermolecular α-alkylation with various olefins exclusively in an anti-Markovnikov fashion. The reaction represents a reductive atom transfer radical addition (ATRA) and provides a series of alkylated amides in good yields.
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