Stereoselective synthesis of 6-oxabicyclo[3.2.1]octene via (3,5)-oxonium-ene reaction
2012
Saha, Pipas | Saikia, Anil K.
Oxabicyclo[3.2.1]octene can efficiently be synthesized by the reaction of (−)-terpinen-4-ol and aldehyde or epoxide catalyzed by indium triflate (In(OTf)₃) in good yields. The reaction is stereoselective and proceeds via (3,5)-oxonium-ene-type reaction.
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