Stereoselective Total Synthesis of Bioactive Marine Natural Product Biselyngbyolide B
2016
Das, Sayantan | Paul, Debobrata | Goswami, Rajib Kumar
A convergent strategy for the stereoselective total synthesis of biologically active marine natural product biselyngbyolide B has been developed. Key strategies of this synthesis include Jamison protocol of trans-hydroalumination/allylation for installation of C₁₈–C₂₃ olefin moiety and intramolecular Heck coupling for macrocyclization.
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