Stereoselective synthesis of tetrahydropyran–tetrahydrofuran (THP–THF) core of (+)-muconin via Prins cyclization
2014
Yadav, J.S. | Reddy, U.V Subba | Reddy, B.V Subba
A stereoselective synthesis of tetrahydropyran–tetrahydrofuran (THP–THF) core 2 of (+)-muconin (1) has been achieved using Prins cyclization as a key step to construct tetrahydropyran moiety. Other important transformations such as Wittig olefination, Sharpless epoxidation, regio-, and stereoselective exo-cyclization of the epoxy alcohol, titanocene induced regioselective deoxygenation of 2,3-epoxy alcohol, Grignard reaction, and Barton–McCombie reaction are successfully employed to accomplish the synthesis of THP–THF core 2.
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