[2]Catenanes Displaying Switchable Gin-Trap-Like Motion
2018
Tsai, Chi-You | Lai, Chien-Chen | Liu, Yi-Hung | Peng, Shie-Ming | Cheng, Richard P. | Chiu, Sheng-Hsien
Sodium ion-controlled switching from “folded” to “linear” states results in significant changes in the molecular shape of a [2]catenane, such that it mimics the operation of a gin trap, with a fluorescent alarm signal appearing when pyrene side arms were present on its two macrocyclic components.
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