Total Synthesis of (±)-δ-Rubromycin
2013
Wang, Wenjing | Xue, Jijun | Tian, Tian | Zhang, Jie | Wei, Liping | Shao, Jidong | Xie, Zhixiang | Li, Ying
Transition-metal-catalyzed spiroketalization cyclization has been performed successfully and has led to the first total synthesis of (±)-δ-rubromycin with a longest linear sequence of 18 steps from commercially available guaiacol in a 2.7% overall yield.
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