NaH-mediated direct C–H arylation in the presence of 1,10-phenanthroline
2020
Nozawa-Kumada, Kanako | Iwakawa, Yuki | Onuma, So | Shigeno, Masanori | Kondō, Yoshinori
Transition-metal-free coupling of haloarenes with unactivated arenes has been developed in the presence of NaH and 1,10-phenanthroline. Various haloarenes bearing methyl, methoxy, halogen (fluoride, chloride, and bromide), cyano, trifluoromethyl, ester, and amide groups can be cross-coupled with unactivated arenes, or heteroarenes in this reaction.
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