Meta-Selective C–H Functionalization Using a Nitrile-Based Directing Group and Cleavable Si-Tether
2013
Lee, Sunggi | Lee, Hyelee | Tan, Kian L.
A nitrile-based template that enables meta-selective C–H bond functionalization was developed. The template is applicable to a range of substituted arenes and tolerates a variety of functional groups. The directing group uses a silicon atom for attachment, allowing for a facile introduction/deprotection strategy increasing the synthetic practicality of this template.
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