CARS Investigation of Changes in Chromophore Geometry of C-Phycocyanin from Mastigocladus laminosus Induced by Titration with p-Chloromercuribenzenesulfonate
2014
Schneider, S. | Baumann, F. | Klüter, U.
Titration of trimers of C-phycocyanin with p-chloromercuribenzenesulfonate (PCMS) changes spectroscopic and kinetic properties of chromophore B84. The resonance-enhanced CARS spectra of room temperature solutions indicate that these changes are due to a modification in B84 chromophore geometry (movement of ring D) as judged by the disappearance of the 1245 cm⁻¹ vibration.
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