Degradation of triclosan in the presence of p-aminobenzoic acid under simulated sunlight irradiation
2017
Zhai, Pingping | Chen, Xuan | Dong, Wenbo | Li, Hongjing | Chovelon, Jean-marc
This study aimed to investigate the degradation of triclosan (TCS) in the presence of p-aminobenzoic acid (PABA) under simulated sunlight irradiation (λ ≥ 290 nm). The effect of PABA concentration, pH, dissolved organic matter (DOM), and DOM-hydrolytic Fe(III) species complexes on the photodegradation of TCS in the presence of PABA (TCS₋PABA) was also studied. The photolysis of TCS₋PABA obeyed pseudo-first-order kinetics well, and the degradation of TCS₋PABA enhanced with increasing solution pH (from 3.0 to 11.0). The presence of PABA inhibited the degradation of TCS₋PABA, and the weakest inhibitory effect was observed while the concentration of PABA was 5 mg L⁻¹. The addition of DOM (Suwannee River fulvic acid standard I [SRFA], Suwannee River HA standard II [SRHA], and Suwannee River natural organic matter [SRNOM]) showed different inhibition effects on TCS₋PABA degradation. However, higher Fe(III) concentration at the DOM concentration of 5 mg L⁻¹ could favor the formation of DOM-hydrolytic Fe(III) species complexes, further accelerating the degradation of TCS₋PABA. In comparison with deionized water (DI water), TCS₋PABA could be better photodegraded in river water nearby the effluent of a wastewater treatment plant. This study provides useful information for understanding the natural behavior of TCS in the presence of other organic contaminants.
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