Synthesis of the putative structure of tridachiahydropyrone

Jeffery, D.; Perkins, M.; White, J.

Synthesis of the putative structure of tridachiahydropyrone

2005

Jeffery, D. | Perkins, M. | White, J.

[reaction: see text] A short total synthesis of the putative structure of the marine natural product tridachiahydropyrone as a single enantiomer is described. Novel steps include a cuprate addition and cyclization to form a cyclohexanone ring and formation of the bicyclic pyrone with P(2)O(5) on Celite. The spectroscopic data obtained for compound 1 do not match those reported for tridachiahydropyrone; therefore, revision of the assigned natural product structure is warranted.

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David W. Jeffery, Michael V. Perkins, and Jonathan M. White

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Mots clés AGROVOC

animals mollusca

Informations bibliographiques

Editeur

Amer Chemical Soc

D'autres materias

Cyclization; Nuclear magnetic resonance; Pyrones; Stereoisomerism; Biomolecular; Molecular structure

Langue

anglais

Licence

ISSN

1581-1584, 1523-7060, 1523-7052, 0000-0002, 7054-0374

Type

Journal Article; Journal Part

Source

https://doi.org/10.1021/ol050236d

Sur AGRIS depuis: 2024-10-18

Date de modification: 2025-04-17

Format: Dublin Core

Fournisseur de données

Cette notice bibliographique a été fournie par University of Adelaide

Découvrez la collection de ce fournisseur de données dans AGRIS

Liens

DOI http://hdl.handle.net/2440/66396

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Synthesis of the putative structure of tridachiahydropyrone

2005

Mots clés AGROVOC

Informations bibliographiques