Assessment of Contamination along the Tigris River from Tharthar-Tigris Canal to Azizziyah, Middle of Iraq

The Tigris River is the second-longest river in Western Asia and runs through heavily populated areas, especially in Baghdad city with nearly 8 million inhabitants. The water demand is at its highest levels, nevertheless the Tigris discharge has severely declined in the last decades; combined with the fact that the wastewater quantities are increasing, and the wastewater treatment plants are experiencing a deficiency. Four sites were chosen: the Tharthar-Tigris Canal which is located in the north part of Baghdad city, Baghdad city, the Diyala River conjunction with the Tigris River site, and Al-Azizziyah site in the south of Baghdad city near Kut government, to determine the effect of the decreasing Tigris River flow on the water quality and to identify the sources of pollution. In this research, the used method evaluates the concentration of the contaminants along the course of the Tigris River to determine the source of the contaminants as the novelty of this research. The data include the discharge of The Tigris River, a hydrochemical analysis, such as major ions and trace elements, and biological parameters (BOD₅, COD, <i>E. coli</i> bacteria, and coliform bacteria MPN/100 mL) as contamination indicators. Multivariate statistical techniques (factor analysis) were applied to evaluate spatial variations, for the years 2005 to 2020, and Phreeqc software was used to assess the saturation indices determine the dominant geochemical processes source responsible for surface water quality. The dominant minerals of the Tigris River were gypsum, anhydrite, and halite. The Tigris River is within the permissible limits for drinking, except at the Tharthar-Tigris Canal and Diyala River, and the main water quality deterioration factors of the Tigris River were recognized as: total dissolved solids, <i>E. coli</i> bacteria, fecal coliform bacteria, BOD₅, and COD. By applying the SPSS program, two factors were identified. The first anthropogenic factor discharged into the river represents 71.27% of the variance and is comprised of agricultural land wastewater and sewage water. While the second factor represents 17.02%, indicated by the variables Ca²⁺, K⁺, Mg²⁺, and SO₄²⁻. This factor accounts for the chemical weathering of rocky components. It is recommended that a periodic monitoring system is needed to_. follow up on pollution levels and water quality for the Tigris River, by conducting seasonal surveys.