Lab-scale investigation of the ability of Polar Organic Chemical Integrative Sampler to catch short pesticide contamination peaks
2022
Bernard, Marion | Boutry, Sébastien | Tapie, Nathalie | Budzinski, Hélène | Mazzella, Nicolas | Ecosystèmes aquatiques et changements globaux (UR EABX) ; Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE) | Institut des Sciences Moléculaires (ISM) ; Université de Bordeaux (UB)-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) | Laboratoire de Physico et Toxico-Chimie des systèmes naturels (LPTC) ; Université Sciences et Technologies - Bordeaux 1 (UB)-Centre National de la Recherche Scientifique (CNRS) | ANR-11-CESA-0022,PoToMAC,Potentiel Toxique dans les Milieux Aquatiques Continentaux : échantillonnage passif des pesticides et relations exposition/impacts sur les biofilms(2011)
[Departement_IRSTEA]Eaux [ADD1_IRSTEA]Systèmes aquatiques soumis à des pressions multiples
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Afficher plus [+] Moins [-]anglais. In this lab-scale study, the POCIS capacity to integrate short contamination peaks of variable intensity and duration was evaluated. POCIS were immersed for 14 days in tanks filled with tap water and spiked at different concentrations with 12 pesticides of various polarities (log Kow = 1.1'4.7) and classes (herbicides, fungicides, and insecticides). Concentrations were kept relatively constant at 1 µg L'1 and 5 µg L'1, respectively, in two 'background' exposure tanks. Three contamination peaks of increasing intensity and decreasing duration were simulated (10 µg L'1 for 24 h, 40 µg L'1 for 6 h, and 60 µg L'1 for 1 h). This lab-scale study demonstrated that ten moderately polar compounds (2 < log Kow < 4) showed a linear uptake, as observed in previous studies, while a non-linear model fits the data of the two most polar pesticides (log Kow < 2). Depending on chemical polarity, some compounds exhibited a 'burst effect' or 'lag effect' during the first 3 days of exposure. After 14 days of exposure, contamination peaks appeared integrated for seven compounds, showing the ability of POCIS to catch very short pollution events and to provide acceptable time-weighted average concentration estimates under laboratory-controlled conditions.
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