Synthesis and Application of FeMg-Modified Hydrochar for Efficient Removal of Lead Ions from Aqueous Solution
2025
Jelena Petrović | Marija Koprivica | Marija Ercegović | Marija Simić | Jelena Dimitrijević | Mladen Bugarčić | Snežana Trifunović
This study explores the utilization of waste grape pomace-derived hydrochar as an efficient adsorbent for lead (Pb2+) removal from aqueous solutions. Hydrochar was produced via hydrothermal carbonization (HTC) at 220 °:C, followed by doping with magnesium and iron salts, and subsequent pyrolysis at 300 °:C to obtain Fe/Mg-pyro-hydrochar (FeMg-PHC). The material&rsquo:s structural and morphological changes after Pb2+ adsorption were examined using FTIR. FTIR revealed chemisorption and ion exchange as key mechanisms, shown by decreased hydroxyl, carbonyl, and metal&ndash:oxygen peaks after Pb2+ adsorption. Adsorption tests under varying pH, contact time, and initial Pb2+ concentrations revealed optimal removal at pH 5. Kinetic modeling indicated that the process follows a pseudo-second-order model, suggesting chemisorption as the dominant mechanism. Isotherm analysis showed that the Sips model best describes the equilibrium, with a maximum theoretical adsorption capacity of 157.24 mg/g. Overall, the simple two-step synthesis&mdash:HTC followed by pyrolysis&mdash:combined with metal doping yields a highly effective and sustainable adsorbent for Pb2+ ion removal from wastewater.
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