Global fate and transport of γ-HCH and DDT was studied using a global multicompartment chemistry-transport model, MPI-MCTM, with and without inclusion of land ice (in Antarctica and Greenland) or snow cover (dynamic). MPI-MCTM is based on coupled ocean and atmosphere general circulation models. After a decade of simulation 4.2% γ-HCH and 2.3% DDT are stored in land ice and snow. Neglection of land ice and snow in modelling would underestimate the total environmental residence time, τₒᵥ, of γ-HCH and overestimate τₒᵥ for DDT, both on the order of 1% and depending on actual compartmental distribution. Volatilisation of DDT from boreal, seasonally snow covered land is enhanced throughout the year, while volatilisation of γ-HCH is only enhanced during the snow-free season. Including land ice and snow cover in modelling matters in particular for the Arctic, where higher burdens are predicted to be stored.

The distribution of antimony (Sb) in topsoil and moss (Dicranum angustum) in disturbed and undisturbed areas, as well as coal and gangue, in Ny-Ålesund, Arctic was examined. Results show that the weathering of coal bed could not contribute to the increase of Sb concentrations in topsoil and moss in the study area. The distribution of Sb is partially associated with traffic and historical mining activities. The occurrence of the maximum Sb concentration is due to the contribution of human activities. In addition, the decrease of Sb content in topsoil near the coastline may be caused by the washing of seawater. Compared with topsoils, moss could be a useful tool for monitoring Sb in both highly and lightly polluted areas.

Atmospheric concentrations of halogenated flame retardants (FRs) were monitored for approximately one year at two remote stations, namely Nam Co on the Tibetan Plateau and Alert in the Canadian High Arctic. BDE-47 and 99 were the dominant polybrominated diphenyl ether (PBDE) congeners at both sites. Atmospheric PBDE concentrations in Nam Co were generally lower than those at Alert. While significant seasonal variations were observed for PBDEs at Alert, the FR concentrations at Nam Co showed no significant seasonality, even though air masses originated from distinctly different regions during different seasons. This suggests that FRs in Tibet do not have regional sources, but are reflective of truly global background contamination. Three new FRs, namely 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE), 2-ethyl-1-hexyl-2,3,4,5-tetrabromobenzoate (EHTeBB) and bis(2-ethyl-1-hexyl)tetrabromophthalate (TBPH) were detected at relatively high concentrations at both sites. This is the first report of these FRs in the remote global atmosphere and suggests significant potential for long-range atmospheric transport.

Organochlorine compounds (OC) were determined in Arctic bivalves (Mya truncata, Serripes groenlandicus, Hiatella arctica and Chlamys islandica) from Svalbard with regard to differences in geographic location, species and variations related to their size and age. Higher chlorinated polychlorinated biphenyls (PCB 101–PCB 194), chlordanes and α-hexachlorocyclohexane (α-HCH) were consistently detected in the bivalves and PCBs dominated the OC load in the organisms. OC concentrations were highest in Mya truncata and the lowest in Serripes groenlandicus. Species-specific OC levels were likely related to differences in the species’ food source, as indicated by the δ¹³C results, rather than size and age. Higher OC concentrations were observed in bivalves from Kongsfjorden compared to the northern sampling locations Liefdefjorden and Sjuøyane. The spatial differences might be related to different water masses influencing Kongsfjorden (Atlantic) and the northern locations (Arctic), with differing phytoplankton bloom situations.

A selection of PCN congeners was analyzed in pooled blubber samples of pilot whale (Globicephala melas), ringed seal (Phoca hispida), minke whale (Balaenoptera acutorostrata), fin whale (Balaenoptera physalus), harbour porpoise (Phocoena phocoena), hooded seal (Cystophora cristata) and Atlantic white-sided dolphin (Lagenorhynchus acutus), covering a time period of more than 20 years (1986–2009). A large geographical area of the North Atlantic and Arctic areas was covered. PCN congeners 48, 52, 53, 66 and 69 were found in the blubber samples between 0.03 and 5.9 ng/g lw. Also PCBs were analyzed in minke whales and fin whales from Iceland and the total PCN content accounted for 0.2% or less of the total non-planar PCB content. No statistically significant trend in contaminant levels could be established for the studied areas. However, in all species except minke whales caught off Norway the lowest ∑PCN concentrations were found in samples from the latest sampling period.

The global distribution and long-range transport of polyfluoroalkyl substances (PFASs) were investigated using seawater samples collected from the Greenland Sea, East Atlantic Ocean and the Southern Ocean in 2009–2010. Elevated levels of ΣPFASs were detected in the North Atlantic Ocean with the concentrations ranging from 130 to 650 pg/L. In the Greenland Sea, the ΣPFASs concentrations ranged from 45 to 280 pg/L, and five most frequently detected compounds were perfluorooctanoic acid (PFOA), perfluorohexanesulfonate (PFHxS), perfluorohexanoic acid (PFHxA), perfluorooctane sulfonate (PFOS) and perfluorobutane sulfonate (PFBS). PFOA (15 pg/L) and PFOS (25–45 pg/L) were occasionally found in the Southern Ocean. In the Atlantic Ocean, the ΣPFASs concentration decreased from 2007 to 2010. The elevated PFOA level that resulted from melting snow and ice in Greenland Sea implies that the Arctic may have been driven by climate change and turned to be a source of PFASs for the marine ecosystem.

Levels and trends of persistent organic pollutants and trace elements in seabirds breeding in the vast Canadian Arctic have been monitored since 1975. Data from this monitoring have indicated both spatial and temporal variation across the region, attributable in part to differences in species’ diets, differences in regional deposition patterns, and unidirectional trends in contaminants reaching this area from emissions in temperate and tropical areas to the south. Seabird tissues have served as effective biomonitors to examine this variation, and national and international collaboration in this monitoring effort has promoted valuable synthetic assessments of spatial and temporal patterns in Arctic contaminants. Here we review the history of the monitoring program, the critical role played by Environment Canada’s National Wildlife Specimen Bank, and we summarize important spatial and temporal trends in various contaminants in Canadian Arctic seabirds.

Concentrations of Fe, As, Ba, Cd, Cu, Cr, Pb, Mn, Ni, Sn, V and Zn in mud (<63μm size), and total and methyl Hg in gross sediment are reported for Arctic Alaska nearshore. Multivariate-PCA analysis discriminated seven station clusters defined by differences in metal concentrations, attributed to regional variations in granulometry and, as in Elson Lagoon, to focused atmospheric fluxes of contaminants from Eurasia. In Colville Delta-Prudhoe Bay, V increase was noted in 1985 and 1997 compared to 1977, and Ba increase from 1985 to 1997. Presumably the source of increased V is the local gas flaring plant, and the elevated Ba is due to barite accumulation from oil drilling effluents. In Prudhoe Bay, concentration spikes of metals in ∼1988 presumably reflect enhanced metals deposition following maximum oil drilling in 1980s. In summary, the Alaskan Arctic nearshore has remained generally free of metal contamination despite petroleum-related activities in past 40years.

Temporal depositional rates are important in order to understand the production and occurrence of perchlorate (ClO 4 − ) as limited information exists regarding the impact of anthropogenic production or atmospheric pollution on ClO 4 − deposition. Perchlorate concentrations in discrete ice core samples from the Eclipse Icefield (Yukon Territory, Canada) and Upper Fremont Glacier (Wyoming, USA) were analyzed using ion chromatography tandem mass spectrometry to evaluate temporal changes in the deposition of ClO4 − in North America. The ice core samples cover a time period from 1726 to 1993 and 1970 to 2002 for the Upper Fremont Glacier (UFG) and Eclipse ice cores, respectively. The average ClO4 − concentration in the Eclipse ice core for the time period from 1970 to 1973 was 0.6 ± 0.3 ng L−1, with higher values of 2.3 ± 1.7 and 2.2 ± 2.0 ng L−1 for the periods 1982–1986 and 1999–2002, respectively. All pre-1980 ice core samples from the UFG had ClO4 − concentrations <0.2 ng L−1, and the post-1980 samples ranged from <0.2 ng L−1 to a maximum of 2.6 ng L−1 for the year 1992. A significant positive correlation (R = 0.75, N = 15, p < 0.001) of ClO 4 − with SO 4 2− was found for the annual UFG ice core layers and of ClO4 − with SO 4 2− and NO 3 − in sub-annual Eclipse ice samples (R > 0.3, N = 121, p < 0.002). The estimated yearly ClO 4 − depositional flux for the Eclipse ice core ranged from 0.6 (1970) to 4.7 μg m−2 year−1 (1982) and the UFG from <0.1 (pre-1980) to 1.4 μg m−2 year−1 (1992). There was no consistent seasonal variation in the ClO 4 − depositional flux for the Eclipse ice core, in contrast to a previous study on the Arctic region. The presence of ClO 4 − in these ice cores might correspond to an intermittent source such as volcanic eruptions and/or any anthropogenic forcing that may directly or indirectly aid in atmospheric ClO 4 − formation.

According to the European legislation, REACH, organic compounds are considered as substances of very high concern (SVHC) if they are persistent, bioaccumulative and toxic (PBT). A substance’s long-range transport potential (LRTP) may also pose a risk to remote regions. This is, however, not yet explicitly included. For identification of compounds, which are not PBT according to REACH criteria, but show LRTP, we investigated 22,438 compounds from the Canadian Domestic Substance List (CDSL). The CDSL was searched for organic, neutral compounds. Substance properties were estimated with EPI Suite v4.00. Next, the substance list was edited in two ways: (1) The half-life criterion in air for LRTP as defined in the Stockholm Convention was applied. (2) For all compounds, indicators for persistence and LRTP were calculated with the multimedia model ELPOS v2.2. Applying the half-life criterion, we identified 594 substances, which are prone to LRT but are not PBT (non-PBT-L substances). In contrast, investigations with ELPOS lead to a shorter list of 188 substances, which are non-PBT-L substances. Finally, the list was compared with potential Arctic contaminants identified in previous literature. Our results show that there is a large number of organic chemicals which would not be considered as SVHC since they are not, at the same time, persistent, bioaccumulative and toxic according to REACH criteria. Nevertheless, they show LRTP according to different screening approaches and thus a potential hazard to remote regions.