Chromium contamination in water bodies poses severe risks to both the environment and human health. This research introduces an innovative solution to this challenge by creating a vapor-activated carbosorbent from biodegradable household waste. The efficacy of this adsorbent in removing total chromium through batch methods from aqueous solutions was investigated. Surface analysis using scanning electron microscopy (SEM) exhibited a porous structure, while Fourier-transform infrared spectroscopy (FTIR) identified distinct functional groups on the surface. The point of zero charge (PZC), determined at 6.95, revealed the adsorbent’s surface chemistry. Impressively, the synthesized carbosorbent exhibited significant adsorption capacities of 23.08 mg.g-1 for Cr(III) and 24.84 mg.g-1 for Cr(VI) under optimal conditions. The Langmuir isotherm model illustrated a monolayer adsorption mechanism aligned with the pseudo-second-order kinetic model, confirming chemisorption. Thermodynamic analysis disclosed favorable and spontaneous chromium adsorption. Negative ΔG° values affirmed the spontaneity, while the exothermic nature of the process was signified by the positive ΔH° value, indicating heat release. Increased randomness at the solid-liquid interface, indicated by the positive ΔS° value, underscored the enhanced affinity between the adsorbent and adsorbate. This study exemplifies the potential of the vapor-activated carbosorbent as an efficient and sustainable remedy for chromium-contaminated water bodies.

Tannery wastewater contains a significant amount of chemical compounds, including toxic substances. Due to the toxicity and negative environmental effects of these tannery effluents, mandatory treatment is necessary. The main objective of this study was to treat effluent from an artisanal tannery in the city of Fez (Morocco) using the adsorption process with activated charcoal derived from olive pomace. The physicochemical characterization of tanning water included several parameters, such as chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), suspended solids (SS), sulfate ions (SO42-), nitrate, and chromium Cr(VI). The analyses show that the adsorption process reduced nitrate by 57.54%, sulfate by 94.08%, TKN by 74.84%, COD by 68.18%, Cr by 91.27%, and Cr (VI) by 89.78%. The activated charcoal was characterized before and after tannery effluent treatment using various techniques, including FT-IR, SEM, and EDX. From the above, it can be inferred that using activated carbon made from olive pomace has the potential to reduce tannery effluent pollution parameters. This innovative approach demonstrates that competitive results can be achieved without sacrificing economic viability, thereby promoting sustainable practices in the treatment of industrial liquid waste and wastewater treatment plants.