Synthetic fibers with diameters of several tens of micrometers are the most abundant type of microplastics in the marine environment, yet the most unknown regarding dynamics in the water column. Experiments proposed here are a proof-of-concept of qualitative and quantitative characteristics of fibers’ motion in still water and in the presence of thermal convection. For 12 sets of fine fibers (nylon (1.12 g/cm³) and polyester (1.35 g/cm³), 1.9–14.8 mm long, diameters 13 and 20 μm), 84 measurements of sinking velocity in still water were acquired. In still conditions, fibers settled smoothly and slowly, preserving their initial (accidental) orientation. Sinking rates of fibers with lengths <5 mm varied between 0.5 and 3.7 mm/s (the bulk mean of 1.6 mm/s). Fibers with similar properties showed 4-fold different sinking velocity, which is supposed to be the effect of their different orientation while settling: vertically oriented fibers (19% in the experiments) settled faster than those with inclined orientation (48%), and horizontally oriented fibers (33%) settled with the smallest velocities.Convective mixing of water, heated from below, principally changed the manner of sinking of fibers: their motions became unsteady and 3-dimensional. In 78 measurements for 4-mm long nylon fibers (using the “light knife” technique), only about 56% of fibers showed downward velocity component (mean 1.33 ± 0.78 mm/s), which was twice as small as in still water, however the ratio of max/min values increased up to 14. Fibers could move in different directions and follow circular motions of a convective cell. Our findings suggest two possible mechanisms retaining fibers in the water column: entrainment of some particles in horizontal and vertical motions and slowed sinking due to unsteady flow around the fiber. The retention of fibers leads to decrease in integral downward particle flux (up to 4 times in our experiments).

In recent years, there has been a sharp increase in interest in the development of environmentally friendly technology for burning methane gas hydrate. In addition to solving energy problems, gas hydrates will help to make significant progress in solving environmental problems. The use of gas hydrate combustion technology is shown to reduce harmful emissions. In this work, experimental studies on the combustion of double hydrate powder of propane-methane have been performed at five different ways of combustion organization. Powder heating was realized using: 1) induction heating; 2) radiation and convective heating; 3) using a hot metal body; 4) combustion without forced gas flow and 5) combustion in the presence of forced and free air convection. Currently there has been neither a comprehensive study of the combustion of double gas hydrates, nor a comparison of the combustion efficiency for different methods; besides, no data on emissions have been obtained. The maximum dissociation rate is implemented with the use of induction heating. Using a gas analyzer the concentration of gases during the gas hydrate combustion has been measured. Comparison of different ways of combustion allows optimizing the combustion efficiency of gas hydrates.

Diel methane emission fluxes from a landfill that was covered by vegetation were investigated to reveal the methane emission mechanisms based on the interaction of vegetation characteristics and climate factors. The methane emissions showed large variation between daytime and nighttime, and the trend of methane emissions exhibited clear bimodal patterns from both Setaria viridis- and Neyraudia reynaudiana-covered areas. Plants play an important role in methane transportation as well as methane oxidation. The notable decrease in methane emissions after plants were cut suggests that methane transportation via plants is the primary way of methane emissions in the vegetated areas of landfill. Within plants, the methane emission fluxes were enhanced due to a convection mechanism. Given that the methane emission flux is highly correlated with the solar radiation during daytime, the convection mechanism could be attributed to the increase in solar radiation. Whereas the methane emission flux is affected by a combined impact of the wind speed and pedosphere characteristics during nighttime. An improved understanding of the methane emission mechanisms in vegetated landfills is expected to develop a reliable model for landfill methane emissions and to attenuate greenhouse gas emissions from landfills.

Trace elements (TEs) in the insoluble particles of surface snow are less affected by melting processes and can be used as environmental proxies to reveal natural and anthropogenic emissions. Here the first comprehensive study of the 16 TEs (Al, As, Ba, Bi, Cr, Cu, Fe, Mn, Ni, Pb, Sn, Sr, Ti, U, V, and Zn) in insoluble particles (>0.45 μm) from surface snow samples collected at Urumqi Glacier No. 1 (UG1), Eastern Tien Shan, China, from February 2008 to January 2010 were presented. Results show that concentrations of most insoluble particulate TEs (TEs ᵢₙₛₒₗ) in the snow were higher in summer while lower in winter, due to the increasing particle inputs and melting processes. The abundances of As, Cr, Cu, Ni, Pb, and Zn in some samples were higher than those in surrounding urban soils, which might due to these TEs have further anthropogenic input beyond the already contaminated re-suspended urban soil particles and TEs were mainly enriched in particles with small grain size. Based on enrichment factor (EF) and principal component analysis (PCA), our results suggest that eight TEs (Al, Fe, Ti, Ba, Mn, Sr, U, and V) mainly came from mineral dust, while the remaining eight TEs (As, Bi, Cr, Cu, Ni, Pb, Sn, and Zn) were affected by coal combustion, mining and smelting of non-ferrous metals, traffic emissions, and the steel industry. The Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model suggests that pollutants might originate from Xinjiang province, Kazakhstan, and Kyrgyzstan. Moreover, UG1 received more significant inputs of particle-bound pollutants in summer than in winter due to the stronger convection and the prevailing valley wind that transports pollutants from the city of Urumqi.

Evaluating the fate and transport of nanoparticles (NPs) in the subsurface environment is critical for predicting the potential risks to both of the human health and environmental safety. It is believed that numerous environmental factors conspire to control the transport dynamics of nanoparticles, yet the effects of organic phosphates on nanoparticles transport remain largely unknown. In this work, we quantified the transport process of TiO2 nanoparticle (nTiO2) and their retention patterns in water-saturated sand columns under various myo-inositol hexakisphosphate (IHP) or phosphate (Pi) concentrations (0–180 μM P), ferrihydrite coating fractions (λ, 0–30%), ionic strengths (1–50 mM KCl), and pH values (4–8). The transport of nTiO2 was enhanced at increased P concentration due to the enhanced colloidal stability. As compared with Pi at the equivalent P level, IHP showed stronger effect on the electrokinetic properties of nTiO2 particles due to its relatively more negative charge and higher adsorption affinity, thereby facilitating the nTiO2 transport (and thus reduced retention) in porous media. At the IHP concentration of 5 μM, the retention of nTiO2 increased with increasing λ and ionic strength, while decreased with pH. In addition, the retention profiles of nTiO2 showed a typical hyperexponential pattern for most scenarios mainly due to the unfavorable attachment, and can be well described by a hybrid mathematical model that coupled convection dispersion equations with a two-site kinetic model and DLVO theory. These quantitative estimations revealed the importance of IHP on affecting the transport of nTiO2 typically in phosphorus-enriched environments. It provides new insights into advanced understanding of the co-transport of nanoparticles and phosphorus in natural systems, essential for both nanoparticle exposure and water eutrophication.

Potential utilities of instrumented lightweight unmanned aerial vehicles (UAVs) to quickly characterize tropospheric ozone pollution and meteorological factors including air temperature and relative humidity at three-dimensional scales are highlighted in this study. Both vertical and horizontal variations of ozone within the 1000 m lower troposphere at a local area of 4 × 4 km² are investigated during summer and autumn times. Results from field measurements show that the UAV platform has a sufficient reliability and precision in capturing spatiotemporal variations of ozone and meteorological factors. The results also reveal that ozone vertical variation is mainly linked to the vertical distribution patterns of air temperature and the horizontal transport of air masses from other regions. In addition, significant horizontal variations of ozone are also observed at different levels. Without major exhaust sources, ozone horizontal variation has a strong correlation with the vertical convection intensity of air masses within the lower troposphere. Higher air temperatures are usually related to lower ozone horizontal variations at the localized area, whereas underlying surface diversity has a week influence. Three-dimensional ozone maps are obtained using an interpolation method based on UAV collected samples, which are capable of clearly demonstrating the diurnal evolution processes of ozone within the 1000 m lower troposphere.

Hydrodynamics and associated environmental processes have always been of major concern to coastal-dependent countries, such as Kuwait. This is due to the environmental impact that accompanies the economic and commercial activities along the coastal areas. In the current study, a three-dimensional numerical model is utilized to unveil the main dynamic and physical properties of Kuwait Bay during the critical season. The model performance over the summer months (June, July and August 2012) is assessed against comprehensive field measurements of water levels, velocity, temperature and salinity data before using the model to describe the circulation as driven by tides, gravitational convection and winds. The results showed that the baroclinic conditions in the Bay are mainly determined by the horizontal salinity gradient and to much less extent temperature gradient. The gradients stretched over the southern coast of the Bay where dense water is found at the inner and enclosed areas, while relatively lighter waters are found near the mouth of the Bay. This gradient imposed a reversed estuarine circulation at the main axis of the Bay, particularly during neap tides when landward flow near the surface and seaward flow near the bed are most evident. The results also revealed that the shallow areas, including Sulaibikhat and Jahra Bays, are well mixed and generally flow in the counter-clockwise direction. Clockwise circulations dominated the northern portion of the Bay, forming a sort of large eddy, while turbulent fields associated with tidal currents were localized near the headlands.

A dust storm was observed at the Semi-Arid Climate and Environment observatory of Lanzhou University (SACOL) using a dual-wavelength lidar and an aethalometer from 16 March to 22 March 2010. After the arrival of the dust storm, the lidar backscattered signal increased suddenly, the volume depolarization ratio ranged from 0.2 to 0.4. The dust aerosol was detected mainly in a layer below 2.5 km altitude. A higher attenuated backscatter coefficient (0.005–0.02 km−1/sr) was distributed in a lower layer (below 2.5 km) during the dust storm. The evolution of the dust storm was also clearly revealed by the integrated particle backscatter coefficient (BE). Particles in the coarse mode are predominant during the dust storm because Ångström exponent mainly ranged from 0.5 to 1.0. An aethalometer was used to measure the aerosol absorption coefficient as well as aerosol mass concentration. The average mass concentration of aerosol was 1.3 μg/m3 during the dust free period but increased to 1.8 μg/m3 during the dust storm, so the dust aerosol apparently played an important role. The main absorptive particle was black carbon during the dust free period. In addition, the peaks of dust aerosol concentration mainly occurred at around 08:00 and 20:00 (Beijing Time), one reason was that the increase of wind speed result in more dust particles blown up into the atmosphere in the neighborhood of SACOL and another reason was that the boundary layer convection was undeveloped in the morning and the temperature inversion appeared easily in the evening. The trend of the aerosol absorption coefficient was similar to that of mass concentration, and the aerosol absorption coefficient significantly increased during the dust storm.

PURPOSE OF REVIEW: Atmospheric aerosol from both natural and anthropogenic activities has long been acknowledged as one of the important factors influencing regional and global climate change. Many regions around the globe experienced high aerosol loadings because of intensive emissions, yet the roles of atmospheric aerosols in extreme meteorological and air pollution events have not been well demonstrated due mainly to the complexity of atmospheric physical and chemical interaction at mesoscale and even microscale. Here, we present a comprehensive review of current understanding on the role of atmospheric aerosols in the development and evolution of extreme meteorological events, including monsoon circulation, heat waves, extreme rainfall, tornadoes, and severe air pollution. RECENT FINDINGS: Aerosols could participate in the development of meteorological systems through direct and indirect effects. Large-scale precipitation from shallow stratiform clouds was found to be suppressed by aerosols, while invigoration effects contribute to deep convection and even catastrophic floods in local areas. The occurrence of high-impact weather such as tornadoes and tropical cyclone is also related to aerosol concentration and distribution. Moreover, a positive feedback between aerosols and boundary layer meteorology is proposed as an important factor conducive to heavy haze pollution over urban areas. The work underscores the great importance of aerosols’ meteorological feedback in extreme weather events. Integrated observations and seamless coupling of meteorology and atmospheric chemistry in models are highlighted for future studies to fill the knowledge gap in current research.

Building-integrated photovoltaic systems’ electrical efficiency decreases when their operating temperature increases. To overcome this drawback, the use of the PCM as a passive method to improve the thermal and electrical performances of the system is highly recommended. Yet pure phase change materials are known for low thermal conductivity. Inserting fins in the PCM enhances its thermal conductivity leading therefore to an improvement in the heat transfer rate. The present investigation carried out the optimization of the BIPV-FPCM system to reduce BIPV system temperature at real Tunisian climatic conditions. The best inclination angle of BIPV-FPCM is carried out. Moreover, the suitable depth of the FPCM box is evaluated. BIPV, BIPV-PCM, and BIPV-FPCM systems are compared. In the present thermodynamic work, the fusion and solidification processes of the FPCM were analyzed. In addition, space between successive fin effect, fin length, and position effect on BIPV electrical and thermal performances had been investigated. Interesting findings showed that the decrease in the tilt angle of the module enhances the heat transfer rate in the FPCM due to the improvement of the convection heat transfer rate in the melted PCM. Thirty degrees is found the most optimal tilt angle with respect to the horizontal where the received solar radiation increases with the decrease of the tilt angle from 90° to 30°. Results prove that the best fin number to enhance performances of the BIPV-PCM system is 3 where 6 cm is found to be the best PCM box depth. Eventually, fin positioning is so important to improve the rate of heat transfer rate by promoting natural convection in the PCM. Results reveal that “full fins” and “front fins” scenarios are the best cases for improving the melting rate and performances of the BIPV-FPCM system.