Chemical degradation-based methods including oxidation have shown great promise for controlling benzene, toluene, ethylbenzeneandxylene isomers (BTEX) in waste gas. This study presents an approach in which the emission of BTEX compounds in a bituminous waterproofing (BW) production unit located in the city of Delijan, Iran has been controlled through process modification. The process is modified by introducing a thermal oxidation unit using an incinerator design. The process simulation has been performed with Aspen Hysys software and, key parameters in the oxidation process are identifiedandoptimized. Finally, the environmentalandeconomic performances of the incinerator were assessed to provide a decision support tool for the selection of this approach. Finally, the environmentalandeconomic performances of the incinerator have been assessed to provide a decision support tool for the selection of this approach. The results indicated that the formation of the oxidation unit had prevented the release of BTEX pollutants up to 98.5%. Moreover, the economic analysis illustrated that the rate of return on investment in the proposed project is 0.27. Thus, the potential for attracting capital will have positive impacts on the environmentalandeconomic indicators of the region.

The traditional assessment of agricultural soil remediation technologies pay limited attention to sustainability and only considers the decrease in contaminant concentrations and cost, even though the sustainability of these technologies has been prioritized. This 3-year field study comprehensively assessed the sustainability of four commonly used agricultural soil remediation technologies in terms of metal(loid) removal efficiency, environmental merit, and cost. The farmland was contaminated by previous sewage irrigation with excessive amounts of As, Cd, and Pb. The four selected remediation technologies used were phytoextraction, intercropping of hyperaccumulators and cash crops, chemical immobilization, and turnover and attenuation (T&A). A risk reduction–environmental merit–cost model was utilized to compare these four technologies. Results showed that T&A reduced the health risks posed by excess metal(loid)s by ∼47% and yielded the highest risk reduction and lowest cost. Phytoextraction achieved the highest environmental merit because it produced the least interruption to the environment. A simplified assessment frame for soil remediation technology was established from a retrospective aspect using data from a real soil remediation project. Environmental merit is a less considered factor and more difficult to quantify than risk reduction or cost, thus requiring increased attention.

Accelerating evidence of endocrine-related morbidity has raised alarm about the ubiquitous use of phthalates in the human environment, but studies have not directly evaluated mortality in relation to these exposures. To evaluate associations of phthalate exposure with mortality, and quantify attributable mortality and lost economic productivity in 2013–4 among 55–64 year olds. This nationally representative cohort study included 5303 adults aged 20 years or older who participated in the US National Health and Nutrition Examination Survey 2001–2010 and provided urine samples for phthalate metabolite measurements. Participants were linked to mortality data from survey date through December 31, 2015. Data analyses were conducted in July 2020. Mortality from all causes, cardiovascular disease, and cancer. Multivariable models identified increased mortality in relation to high-molecular weight (HMW) phthalate metabolites, especially those of di-2-ethylhexylphthalate (DEHP). Hazard ratios (HR) for continuous HMW and DEHP metabolites were 1.14 (95% CI 1.06–1.23) and 1.10 (95% CI 1.03–1.19), respectively, with consistently higher mortality in the third tertile (1.48, 95% CI 1.19–1.86; and 1.42, 95% CI 1.13–1.78). Cardiovascular mortality was significantly increased in relation to a prominent DEHP metabolite, mono-(2-ethyl-5-oxohexyl)phthalate. Extrapolating to the population of 55–64 year old Americans, we identified 90,761–107,283 attributable deaths and $39.9–47.1 billion in lost economic productivity. In a nationally representative sample, phthalate exposures were associated with all-cause and cardiovascular mortality, with societal costs approximating $39 billion/year or more. While further studies are needed to corroborate observations and identify mechanisms, regulatory action is urgently needed.

Various oil spill cleanup sorbents have good hydrophobicity and oil separation efficiency, but their practical use has been limited due to the difficult and costly fabrication procedure. The research aims towards material development using the consumption of lignocellulosic agricultural residue for isolating cellulose nanofiber and its forward use to construct a 3D porous structure. A simple freeze-drying technique was used to assemble low-density porous structure. The biodegradable polylactic acid coating was used to alter the wettability from hydrophilic to hydrophobic and the maximum water contact angle value was around 120°. The prepared coated samples were testified for a series of oil/organic solvents-water mixtures. The sorption capacity was in the range of 28–70 g/g. The prepared aerogels were efficiently reused for at least 10 cycles. Developed material was used in continuous oil-water separation to remove oil from the water's surface. The cost analysis was estimated for scaleup production in the future.

The Arctic is an ecologically diverse area that is increasingly vulnerable to damages from oil spills associated with commercial vessels traversing newly open shipping lanes. The significance of such accidents on Arctic marine habitats and the potential for recovery can be examined using ecological risk assessment (ERA) coupled with a dynamic object-oriented Bayesian network (DOOBN). A DOOBN approach is useful to represent the probabilistic relationships inherent in the interactions between key events associated with an oil spill, including oil dispersion from the source, ice-oil slick interactions, seawater-oil slick formation, sedimentation, and exposures to different aquatic life. From such analysis, a probabilistic cost analysis can be performed to examine the theoretical cost of habitat services lost and restored. The application of an ERA-DOOBN model to assess oil spills in the Arctic is demonstrated using a case study. The utility of the model output for determining habitat restoration costs and developing policy guidelines for ecological response measures in the Arctic is also discussed.

Hollow fiber liquid-phase microextraction (HF-LPME) technique was used as a clean-up procedure for the determination of organophosphorus pesticides (OPPs) in fish tissue. In this study, eight OPPs were first extracted with acetone from fish sample, the organic extract after rotatory evaporation was then redissolved with water–methanol (95:5, v/v) solution, followed by polyvinylidene difluoride (PVDF) HF-LPME. Experimental HF-LPME and other sample preparation conditions were carefully investigated and optimized. Under the optimum conditions, good linearity were observed in the range of 20–500ng/g, limits of detections (LODs) were in the range of 2.1–4.5ng/g. The repeatability and recovery of the method also showed satisfactory results. Compared with traditional sample preparation method for the determination of OPPs in fish tissue, the method developed in this study eliminated the solid phase extraction (SPE) step, simplified the sample preparation procedure and lowered the cost of analysis.

Long-line mussel farming has been proposed as a mitigation tool for removal of excess nutrients in eutrophic coastal waters. A full-scale mussel farm optimized for cost efficient nutrient removal was established in the eutrophic Skive Fjord, Denmark where biological and economic parameters related to nutrient removal was monitored throughout a full production cycle (1yr). The results showed that it was possible to obtain a high area specific biomass of 60tWWha−1eqvivalent to a nitrogen and phosphorus removal of 0.6–0.9 and 0.03–0.04tha−1yr, respectively. The analysis of the costs related to establishment, maintenance and harvest revealed that mussel production optimized for mitigation can be carried out at a lower cost compared to mussel production for (human) consumption. The costs for nutrient removal was 14.8€kg−1N making mitigation mussel production a cost-efficient measure compared to the most expensive land-based measures.

The demand for fresh water is rapidly growing as a consequence of the increasing population and urbanization. Tubular solar still offers larger evaporative and condensing surface area as compared to single slope solar still. The aim of this study is to improve the performance of tubular solar still by employing eggshell powder (collected from Babcobb Broilers chicken) as the sensible energy storage material in form of bed, placed inside the basin of still to improve the water production. Results showed that the influence of eggshell powder as energy storage material in the basin improved the average water temperature by 3%, 6.2%, and 3.2% for the water thickness of 10, 15, and 20 mm, respectively. The usage of eggshells as a sensible energy storage in the basin augmented the peak hourly water yield by 67.64% with minimum water thickness. The total observed distillate output from the solar still is 1.45 kg without eggshell powder and 2.67 kg for with eggshell powder in the absorber at the lowest water thickness of 10 mm. TSS with eggshell powder as energy storage has a daily energy efficiency of 48.17%, 42.38%, and 36.38%, respectively, for water thicknesses of 10, 15, and 20 mm in the basin. Water thickness of 10, 15, and 20 mm has performance improvement ratios of 1.83, 1.81, and 1.78, respectively. Using cost analysis, it was found that the cost of drinkable water generated using eggshell as an energy storage material is 0.011$/kg, but the cost of water by traditional still without any storage material was 0.021$/kg.

The insulation materials are used to reduce heat loss to/from the ducts with additional investment. This study introduces an air gap between insulation and duct surface to reduce the quantity of insulation. It uses lifecycle cost (LCC) analysis to determine the economic benefits of the air gap, considering four insulation materials for insulating the duct and natural gas as an energy source for chiller operation. The preliminary data regarding design and operating parameters were obtained from a renowned pharmaceutical company. The duct’s annual energy loss was estimated for given operation hours in a year using the preliminary data and ambient conditions. The estimated energy loss through the duct was fed in LCC analysis to determine the impact of the air gap on optimum insulation thickness (OIT) corresponding to the minimum LCC and payback period. Results revealed that OIT thickness for a duct with an air gap was lower than insulated duct without an air gap, resulting in maximum cost savings within a shorter payback period. Among different insulation materials, insulated duct with expanded polystyrene was investigated as cost-effective insulation material with maximum cost savings of USD (508.8–766.8)/m/year and a payback period of 1.15–1.17 years. On the contrary, the air gap was the most effective in terms of cost savings for the ducts insulated with rock wool. In conclusion, an air gap is a cost-effective design approach for duct applications.