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Anaerobic treatment of wastewaters from alcohol and yeast factories
1999
Klasnja, M. | Sciban, M. (Univerzitet u Novom Sadu, Novi Sad (Yugoslavia). Tehnoloski fakultet)
Alcohol and yeast production is the most important part of the biotechnological production in Yugoslavia, with annual production of 13 667 867 liters of absolute alcohol and of 20 947 490 kg of yeast in the year 1998. Large environmental load is produced by wastewaters from alcohol and yeast factories (512 000 P.E.), especially by alcohol stillage (BOD 40 000 - 50 000 mg/L). Anaerobic treatment is suitable process for treatment of alcohol stillage, and of yeast factory wastewater. In this paper, effects of treatment process (organic load reduction, energy of produced biogas) are discussed; and potential of anaerobic treatment os wastewaters from Yugoslavia's alcohol and yeast factories is reviewed.
Afficher plus [+] Moins [-]Spatial distribution and profile of atmospheric short-chain chlorinated paraffins in the Yangtze River Delta
2020
Niu, Shan | Chen, Ruiwen | Zou, Yun | Dong, Liang | Hai, Reti | Huang, Yeru
Research on the atmospheric occurrence of short chain chlorinated paraffins (SCCPs) in industrialized areas is scarce. In this study, we investigated the concentrations, profile, and spatial distribution of SCCPs in the highly industrialized and developed areas of the Yangtze River Delta (YRD) in China using polyurethane foam passive air samplers. Sampling was performed during two separate periods in 2011. The concentrations of atmospheric SCCPs ranged from 6.1 to 63 ng m⁻³ in summer and 6.2–42 ng m⁻³ in winter. The C₁₀ and C₁₁ groups were the predominant carbon groups in all the samples. Different congener patterns between summer and winter were found, indicating that congeners in the air in winter may be influenced by local and external sources. The highest level of SCCPs was found in Suzhou, which is a highly industrialized area with many manufactories including electronic industries and plastic factories. Higher levels of SCCPs were found in the air than polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polybrominated diphenyl ether (PBDEs), suggesting that the production and use of SCCPs were much higher than prohibited or restricted persistent organic pollutants (e.g., PCBs, OCPs, and PBDEs). Future studies should investigate the different sources of atmospheric SCCPs by conducting a comprehensive assessment of SCCP exposure.
Afficher plus [+] Moins [-]Species and release characteristics of VOCs in furniture coating process
2019
Qi, Yiqing | Shen, Liming | Zhang, Jilei | Yao, Jia | Lu, Rong | Miyakoshi, Tetsuo
Volatile organic compounds (VOCs) are an important factor affecting ambient air quality, and furniture production is one of the important sources of VOC pollution. High VOC concentrations have adverse effects on the environment and worker welfare in furniture factories. In order to control VOC emissions in a furniture workshop, the VOC species and concentration distributions were examined. Qualitative analysis of VOC species was carried out by headspace gas chromatography/mass spectrometry. The results showed that VOCs from a furniture workshop were mainly 12 substances including acetate, toluene, and xylene compounds. The heights and representative positions of VOCs released during the coating process were determined, and the results showed that VOC concentrations depended on environmental and height factors. The concentration of VOCs decreased with increasing altitude and reached a maximum concentration at 0.4 m above the ground. Because the concentration of VOCs varied with temperature, humidity, air pressure, and amount of spray paint, this paper established functional relationships between VOC concentrations and temperature, humidity, air pressure, and amount of spray paint. These results provide a theoretical basis for furniture workshops to automatically monitor and control VOCs.VOCs from the furniture workshop were mainly composed of 10 substances including acetate, toluene, and xylene compounds.
Afficher plus [+] Moins [-]Brominated flame retardants in the surrounding soil of two manufacturing plants in China: Occurrence, composition profiles and spatial distribution
2016
Li, Wen-Long | Liu, Li-Yan | Zhang, Zi-Feng | Song, Wei-Wei | Huo, Chun-Yan | Qiao, Li-Na | Ma, Wanli | Li, Yi-Fan
Surface soil samples were collected surrounding two brominated flame retardants (BFRs) manufacturing plants in China in August 2014 and analyzed for 23 polybrominated diphenyl ethers (PBDEs) and 8 novel brominated flame retardants (NBFRs). BDE209 and decabromodiphenylethane (DBDPE) were the predominant compounds in soil with the median levels of 1600 and 560 ng/g dw, respectively. The PBDEs profiles in soil samples were consistent with that of commercial product (comDecaBDE). The percentage contributions to total PBDEs decreased from higher to lower brominated homologues. Lower concentrations of NBFRs (excluding DBDPE) were detected in soil surrounding the two plants, suggesting they are byproducts or degradation products of the manufacturing activities. The concentrations of most BFRs dropped exponentially within 3–5 km of the manufacturing plants, suggesting recent deposition of these compounds to the soil. Directional distribution indicated that PBDEs and DBDPE concentrations were highest in the north direction of Plants 1. Three-day air parcel forward trajectories confirmed that the air parcel was responsible for the higher concentration of BFRs in the soil of north direction of the plant.
Afficher plus [+] Moins [-]Phosphorus leakage from fisheries sector – A case study in Thailand
2016
Prathumchai, Nuchnapa | Polprasert, Chongchin | Englande, A. J.
Although phosphorus (P) is an essential element needed for all lives, excess P can be harmful to the environment. The objective of this study aims to determine P flows in the fisheries sector of Thailand consisting of both sea and freshwater activities of captures and cultures. Currently, the annual fisheries catch averages 3.44 ± 0.50 Mt. Most comes from marine capture 1.95 ± 0.46 Mt, followed by coastal aquaculture 0.78 ± 0.09 Mt, freshwater aquaculture 0.49 ± 0.05 Mt, and inland capture 0.22 ± 0.01 Mt. Of this total, about 11% is contained in fresh products directly sold in local markets for consumption, while 89% is sent to processing factories prior to being sold in local markets and exported. The quantities of P entering the fisheries sector come from captures, import of fisheries products and feed produced from agriculture. This P input to the fisheries sector is found to average 28,506 t P.y−1 based on the past ten-year records. Of this total, P input from captures accounts for 76%; while, 11% represents aquatic feeds from agriculture and animal manures. About 13% is obtained from the imports of fishery products. Coastal and freshwater aquacultures are found to be P consumers because their feeds are almost all produced from agricultural crops grown inland. Moreover, these activities cause most of P losses, approximately 10,188 t P·y−1, which account for 89% of the total P loss from the fisheries sector. Overall, P in the fisheries sector is found to mobilize through three channels: (a) 44% is consumed within the country; (b) about 16% is exported; and, (c) 40% is lost from the ecosystem. Based on the results of this work it is recommended that future research be directed on ways to minimize P loss and maximize P recycle in Thailand's fisheries sector as to enhance its food security and curtail water pollution.
Afficher plus [+] Moins [-]Storage and source of polycyclic aromatic hydrocarbons in sediments downstream of a major coal district in France
2015
Bertrand, O. | Mondamert, L. | Grosbois, C. | Dhivert, E. | Bourrain, X. | Labanowski, J. | Desmet, M.
During the 20th century, the local economy of the Upper Loire Basin (ULB) was essentially based on industrial coal mining extraction. One of the major French coal districts with associated urban/industrial activities and numerous coking/gas plants were developed in the Ondaine-Furan subbasins, two tributaries of the upper Loire main stream. To determine the compositional assemblage, the level and the potential sources of contamination, the historical sedimentary chronicle of the 16 US EPA priority polycyclic aromatic hydrocarbons (PAHs) has been investigated. PAH concentrations were determined using gas chromatography/mass spectrometry (GC/MS) in a dated core, sampled in the Villerest flood-control reservoir located downstream of the Ondaine-Furan corridor (OFC). The most contaminated sediments were deposited prior to 1983 (Σ16PAHs ca. 4429–13,348 ng/g) and during flood events (Σ16PAHs ca. 6380 ng/g – 1996 flood; 5360 ng/g – 2003 flood; 6075 ng/g – 2008 flood), especially in medium and high molecular weight PAHs. Among them, typical pyrogenic PAHs such as FLT, PYR, BbF and BaP were prevalent in most of the core samples. In addition, some PAHs last decade data is available from the Loire Bretagne Water Agency and were analyzed using high-performance liquid chromatography with postcolumn fluorescence derivatization (HPLC/FLD). These results confirm that the most highly contaminated sediments were found downstream of OFC (Σ16PAHs ca. 2264–7460 ng/g). According to the observed molecular distribution, PAHs are originated largely from high-temperature pyrolytic processes. Major sources of pyrogenic PAHs have been emphasized by calculation of specific ratios and by comparison to reported data. Atmospheric deposition of urban and industrial areas, wood combustion and degraded coal tar derived from former factories of coking/gas plants seem to be the major pyrogenic sources. Specifically, particular solid transport conditions that can occur during major flood events lead us to emphasize weathering of former contamination sources, such as more preserved coal tar.
Afficher plus [+] Moins [-]Polychlorinated naphthalenes (PCNs) in riverine and marine sediments of the Laizhou Bay area, North China
2011
Pan, Xiaohui | Tang, Jianhui | Chen, Yingjun | Li, Jun | Zhang, Gan
PCN congeners were analyzed in marine and riverine sediments of the Laizhou Bay area, North China. Concentrations of PCNs ranged from 0.12 to 5.1 ng g⁻ ¹ dry weight (dw) with a mean value of 1.1 ng g⁻ ¹ dw. The levels of PCNs varied largely, with industrial group approximately ten folds higher than those of the rural in riverine sediment. A strong impact by direct discharge from local factories was suggested. Similar compositional profiles were found within groups. High resemblance of compositional profiles between industrial samples and Halowax 1014 was observed. It was indicated that PCNs in riverine sediments were mainly from release of industrial usage, with additional contributions from industrial thermal process at certain sites. In marine sediments, it was suggested that PCNs along the coast of Laizhou Bay were mainly controlled by riverine input. While in the central bay, PCN distributions were possibly impacted by combined multiple factors.
Afficher plus [+] Moins [-]Reduced bioavailability of polycyclic aromatic hydrocarbons (PAHs) in sediments impacted by carbon manufacturing plant effluent: Evaluation by ex situ passive sampling method
2020
Endo, Satoshi | Yoshimura, Mitsuki | Kumata, Hidetoshi | Uchida, Masao | Yabuki, Yoshinori | Nakata, Haruhiko
Potential risks of polycyclic aromatic hydrocarbons (PAHs) in sediments of a Japanese bay contaminated by carbon manufacturing plant effluent were evaluated by calculating toxicity units (TUs). TUs calculated from the measured whole-sediment concentrations (Cwhole) were often higher than or close to 1, signaling a possible toxicity concern to benthic organisms. In contrast, TUs based on the freely dissolved pore water concentrations (Cfree) measured by an ex-situ passive sampling method with polyethylene strips were 0.0007–0.005, much lower than 1, indicating no effect. We also found that the fractions of black carbon in sediments of the contaminated bay were significantly higher than those of reference sites. Overall, we conclude that carbon manufacturing plant effluent substantially increases Cwhole of PAHs in sediments but also increases the fraction of carbonaceous particles that strongly retain PAHs. As a combined result, bioavailable concentrations (as expressed by pore water Cfree) of PAHs do not increase as much as Cwhole. The results of this study indicate that ecotoxicological risks of PAH contamination by carbon manufacturing plants should be evaluated by directly measuring pore water Cfree instead of Cwhole.
Afficher plus [+] Moins [-]Factory employment exposure and human health: Evidence from rural China
2020
Xu, Xiangbo | Sun, Mingxing | Zhang, Linxiu | Fu, Chao | Bai, Yunli | Li, Chang
Quantitating the health effects of employment history in factories, especially polluting ones, is essential for understanding the benefits or losses of industrialization in rural areas. Using a traced subset of nationwide panel data from 2005 covering five provinces, 101 villages, and 2026 households (collected recently in 2016) and the econometric models, this study estimated the effect of factory employment history on workers' health. The results showed that: the absolute number of factory workers increased from 1998 to 2015, and the proportion of factory workers was 7.68% in 2015; the absolute number and the proportion of farmers decreased from 63.84% in 1998 to 29.06% in 2015. Given that all the respondents live in rural areas, the HlthPlace (the first place the individual went to for their last illness in 2015) was selected as the main dependent variable of interest, and Hlthexp (Healthcare expenditure per person at last illness in 2015) and self-reported health were used as auxiliary dependent variables. The findings revealed that, after controlling the characteristics of individual, household, hospital and area, a one year increase of factory employment history corresponded to a 0.035 level increase in the probability of people choosing high-level hospital (p < 0.01) and a 237.61 yuan increase in healthcare expenditure (p < 0.1). The results also showed the adverse effect of self-reported health on factory employment history (p < 0.01). In addition, the relationship between the farming history and health was evaluated, and the econometric results showed that compared with factory employment history, farming history had opposite impacts on health (p < 0.01). Finally, the robustness check showed that the empirical results were reliable and that the initial results were robust. Generally, this study revealed the effect of overall factory employment on health, which is a useful research supplement to the studies on the health effects of specific pollution exposure.
Afficher plus [+] Moins [-]Dietary exposure and risk assessment of exposure to hexabromocyclododecanes in a Taiwan population
2019
Lee, Ching-Chang | Zhang, Weixiang | Chen, Hsiu-Ling
Hexabromocyclododecane (HBCD) is commonly used in commercial products and factories. HBCDs can be detected in the air, bioaccumulated deposits, water, soil, sediments, and in biota and foodstuffs in the food-chain because they are not chemically bound to the polymer. We determined the levels of α-, β-, and γ-HBCDs in 270 foodstuffs and the doses of HBCDs Taiwanese are normally exposed to. We also wanted to create a strategy of risk management for HBCDs based on margins of exposure (MOE). HBCDs were frequently detectible in fish, seafood, and poultry. Their highest concentrations were in fish, oil, poultry, and livestock. The highest estimated daily intake was in 0- to 3-year-olds (1.576 ng/kg/day), and lower in 3- to 6- (1.064 ng/kg/day), 6- to 12- (0.899 ng/kg/day), and lowest in 12- to 16- (0.632 ng/kg/day) year-olds. The exposure doses to HBCDs indicated no health concern for Taiwanese. Except for fish, significant concentrations of α- and γ-HBCDs were detected in many other foodstuffs, which might indicate that exposure to HBCD is a relatively recent problem. Therefore, one goal of a management policy should be to follow-up the flow direction of HBCDs in Taiwan.
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