We assessed exposure to 39 brominated and 16 organophosphate ester flame retardants (FRs) from both dust and indoor air at seven childcare centres in Seattle, USA, and investigated the importance of nap mats as a source of these chemicals. Many childcare centres serving young children use polyurethane foam mats for the children's naptime. Until recently, the vast majority of these mats sold in the United States contained flame-retarded polyurethane foam to meet California Technical Bulletin 117 (TB117) requirements. With the 2013 update of TB117, allowing manufacturers to meet flammability standards without adding FRs to filling materials, FR-free nap mats have become widely available. We conducted an intervention study by actively switching out FR-treated nap mats with FR-free nap mats and measuring FR levels in indoor air and dust before and after the switch-out. The predominant FRs found in dust and indoor air were 2-ethylhexyl tetrabromobenzoate (EHTBB) and tris(1-chloro-2-propyl) phosphate (TCIPP), respectively. Nap mat samples analysed from four of the six centres contained a Firemaster® mixture, while one mat was predominantly treated with tris(1,3-dichloroisopropyl) phosphate (TDCIPP) and the other contained no detectable target FRs. After replacement, there was a significant decrease (p = 0.03–0.09) in median dust concentrations for bis(2-ethylhexyl) tetrabromophthalate (BEHTBP), EHTBB, tris(4-butylphenyl) phosphate (TBPP), and TDCIPP with reductions of 90%, 79%, 65%, and 42%, respectively. These findings suggest that the nap mats were an important source of these FRs to dust in the investigated childcare environments and that a campaign of swapping out flame-retarded mats for FR-free ones would reduce exposure to these chemicals. While calculated exposure estimates to the investigated FRs via inhalation, dust ingestion, and dermal absorption were below established reference dose values, they are likely underestimated when considering the toddlers' direct contact to the mats and personal cloud effects.

Brominated flame retardants (BFRs) are chemicals employed to lower the flammability of several objects. These endocrine disruptor chemicals are lipophilic and persistent in the environment. Due to these characteristics some have been restricted or banned by the European Union, and replaced by several new chemicals, the novel BFRs (NBFRs). BFRs are widely detected in human samples, such as adipose tissue and some were linked with altered thyroid hormone levels, liver toxicity, diabetes and metabolic syndrome in humans. However, the disturbance in lipid metabolism caused by BFRs with emphases to NBFRs remains poorly understood. In this study, we used a pre-adipocyte (3T3-L1) cell line and a hepatocyte (HepG2) cell line to investigate the possible lipid metabolism disruption caused by four BFRs: hexabromobenzene (HBB), pentabromotoluene (PBT), 2-ethylhexyl-2,3,4,5-tetrabromobenzoate (TBB) and hexabromocyclododecane (HBCD). For that purpose, proliferation and Oil Red O assays, as well as, medium fatty acids profile evaluation using Gas chromatography and RNA extraction for quantitative RT-PCR assays were performed. We detected a significant reduction in the proliferation of preadipocytes and an increased lipid accumulation during differentiation caused by HBB. This BFR also lead to a significant increased expression of IL-1β and decreased expression of PGC-1α and adiponectin. Nevertheless, PBT, TBB and HBCD show to increase lipid accumulation in hepatocytes. PBT also display a significant increase of PPARγ gene expression. Lipid accumulation in the cells can occur by diverse mechanisms depending on the BFR. These results highlight the importance of endocrine disruptor compounds in obesity etiopathogeny.

Hexabromocyclododecane (HBCD) and Tetrabromobisphenol A (TBBP-A) are brominated flame retardants widely used in variety of industrial and consumer products (e.g., automobiles, electronics, furniture, textiles and plastics) to reduce flammability. HBCD and TBBPA can also contaminate the environment, mainly water, dust, air and soil, from which human exposure occurs. This constant exposure has raised some concerns against human health. These compounds can act as endocrine disruptors, a property that gives them the ability to interfere with hormonal function and quantity, when HBCD and TBBPA bind target tissues in the body. Studies in human and animals suggest a correlation between HBCD and TBBPA exposure and adverse health outcomes, namely thyroid disorders, neurobehavior and development disorders, reproductive health, immunological, oncological and cardiovascular diseases. However, in humans these effects are still poorly understood, once only a few data evaluated the human health effects. Thus, the purpose of this review is to present the toxicity effects of HBCD and TBBPA and how these compounds affect the environment and health, resorting to data and knowledge of 255 published papers from 1979 to 2020.

Dispersion modeling is an important decision tool for estimating the impact of human activities on the environment and its populations. However, it was proved by researchers that AERMOD and CALPUFF, the current regulatory models, do not account for the effect of averaging time. In consequence, these models do not have the ability to predict short-term time peak concentrations. This inability arises from the errors in the lateral and vertical dispersion estimates, which are reliable only to predict 10 min or longer average concentrations. In this paper, a novel evaluation based on Irwin (1983) was conducted to investigate the effect of averaging time on the lateral dispersion and maximum concentration estimates. The Pasquill-Gifford, Högström, Draxler (embedded in CALPUFF) and AERMOD lateral dispersion schemes were tested using the Round Hill II experiment, developed to investigate the effects of averaging time on atmospheric transport and diffusion. The observed lateral dispersion was derived from the lateral concentration profiles along 3 sampling arcs (50, 100 and 200 m), measured on 3 different averaging times (0.5; 3 and 10 min). The observed lateral dispersion was compared to those estimates. The results of the comparison show that AERMOD and Draxler correlate better with measured data than the PG and Högström methods. However, their estimates are biased and the magnitude of systematic errors tends to grow as the averaging time decreases. Moreover, AERMOD and Draxler, with Peak-to-Mean (P-M) adjustment, tend to overestimate the lateral dispersion farther from the source and underestimate at downwind distances less than 200 m. The analysis also highlights some concerns on the P-M ratio application due its subjectivity. The present investigation on the effect of short-term averaging times on atmospheric transport and diffusion may help to understand some issues related to the use of dispersion models in the case of flammability, malodor nuisance and toxicity

Chemical recycling is an environmentally friendly method, which is often used for the recycling of plastics included in waste electric and electronic equipment (WEEE), since fuels and secondary valuable materials can be produced. Brominated flame retardants (BFRs) are usually added into these plastics to reduce their flammability; but they are toxic substances. The aim of this work is to examine the thermal behaviour and the products obtained after pyrolysis of polymer blends that consist of acrylonitrile-butadiene-styrene (ABS), high-impact polystyrene (HIPS), polycarbonate (PC) and polypropylene (PP) with composition that simulates real WEEE, in the absence and presence of a common BFR, tetrabromobisphenol A (TBBPA), in order to investigate its effect on pyrolysis products. Blends were prepared via the solvent casting method and the melt-mixing in an extruder; it was revealed that the latter method may be a better choice for blends preparation, since it did not affect the products obtained. The chemical structure of each polymeric blend was identified by Fourier transform infrared spectroscopy (FTIR). Thermal degradation of the blends was evaluated by thermogravimetric (TG) experiments performed using a thermal analyser (TGA) and a pyrolyser for evolved gas analysis (EGA). It was observed that blends had a similar behaviour during their thermal degradation; and in most cases, they followed a one-step mechanism. Pyrolysis products were identified by the pyrolyser combined with a gas chromatographer/mass spectrometer (GC/MS), and comprised various useful compounds, such as monomers, aromatic hydrocarbons and phenolic compounds that could be used as chemical feedstock. Furthermore, it was found that TBBPA affected products distribution by enhancing the formation of phenolic compounds and on the other hand by resulting in brominated compounds, such as dibromophenol.

Research on phase change material (PCM) for thermal energy storage is playing a significant role in energy management industry. However, some hurdles during the storage of energy have been perceived such as less thermal conductivity, leakage of PCM during phase transition, flammability, and insufficient mechanical properties. For overcoming such obstacle, researchers have been concentrating on composite PCM, where PCM is combined with metal or non-metal particles, fibrous materials, expanded or porous materials, and flame retardants. The main purpose of the current paper is to review the properties enhanced paraffin-based composite PCM. In the literature review, paraffin is selected as a thermal energy storage material, which is mixed with property-enhancing material to prepare composite. Structural and thermal properties of composite have been explored with the help of scanning electron microscope, X-ray diffractometer, transmission electron microscope, polarizing optical microscope, Fourier transform infrared spectroscopy, thermogravimetric analysis, and differential scanning calorimetry. Mechanical properties of the material are also portrayed using different testing techniques. Nevertheless, numerical methods have also been adopted for characterization of composite. It is found from the literature review that with incorporation of property-enhancing material, thermal conductivity, phase transition rate, and shape stability of PCM increased at the same time flammability, heat storage capacity, and mechanical properties reduced.

The leakage of toluene from damaged tanks can threaten both workers and the environment; ergo, the effects and consequences of toluene leaks can be modeled and quantified to aid in emergency planning and response management. This study modeled the effects and consequences on various scenarios of toluene release via the ALOHA and PHAST programs: evaporation puddle formation, dispersion of toxic and flammable vapor clouds, the distribution of lethal concentrations, and the probability of death from a toluene leak from a height of 6 m of the tank wall. The outputs of the two modeling programs were analyzed and compared. The results showed that the maximum threat zone distances associated with high hazards of toxicity, flammability, and thermal radiation of toluene were respectively 736, 132, and 52 m in ALOHA and 1626, no result, and 239 m for PHAST from the accident point in the downwind. The highest probability of death was 92%, which occurred at a distance of 1 m in the cold seasons. The output values for the PHAST program were higher than those for ALOHA. The results also showed that the survival zone in which the probability of death was low could be determined from a distance of 51 m onwards. Although the assessment of the results indicated no matching between the results obtained by ALOHA and PHAST, the program outputs could still help decision-makers in emergency response planning and the allocation of medical and support services during emergencies.

This paper presents the environment-friendly mixture compositions of hydrocarbons (HC)– and hydrofluorocarbon (HFC)–based ternary mixtures that can be better alternatives for R134a in domestic refrigeration units. Combustible refrigerant HCs (R290, R600, R600a) and HFCs (R152a and R161) are used along with the dilutants R13I1, R245fa, R134a, R227ea, and R125 and their flammability studies were carried out theoretically. Minimum inerting concentration (MIC) is used to classify the flammable and non-flammable zones of the ternary mixtures. MIC points estimated with modified thermal balance method (MTBM) are compared with 62 experimental data points available in the literature. It was calculated that MTBM predicted the MIC values with in ±9%, for most of the working fluids selected in this study. R13I1 is used along with all the refrigerant (HC and HFC) combinations (as the first dilutant) while the effect of other dilutants on the system performance is carried out theoretically. It is predicted from the flammability diagram (developed in this study) that the inert effect of R227ea is higher than of R245fa, R134a, and R125. It is also observed that the drop in coefficient of performance (COP) is significant with R290/R13I1/R245fa (with increase in R245fa) mixture when compared to other combinations. Finally, mixtures R600a/R13I1/R245fa, R600a/R13I1/R227ea, R600a/R13I1/R134a, R600a/R13I1/R125, R161/R13I1/R134a, R290/R13I1/R125, R161/R13I1/R227ea, and R161/R13I1/R125 are identified as the best environment-friendly mixture compositions as alternatives to R134a. It is also calculated that the mixture R600a/R13I1/R125 possesses COP greater than 10% to R134a at the same working conditions.

Flame retardants (FRs) are additives used in consumer products to reduce flammability, even though they can easily contaminate the indoor environment. Since it is common for people in modern cities to spend up to 85% of time indoors, the quality of the indoor environment is critical for human health. In this study, polybrominated diphenyl ethers (PBDEs), organophosphorus flame retardants (OPFRs), emerging brominated flame retardants (EBFRs), and dechlorane-related compounds (DRCs) were measured in household dust samples (n = 34) from Latvia, followed by human exposure assessment. Among all studied compounds, OPFRs showed the highest concentrations (1380–133,000 ng g⁻¹). Despite the phase-out of PBDEs, they were the second most significant flame retardants in the studied dust samples (468–25,500 ng g⁻¹) and the predominant compound was BDE-209. The concentrations of EBFRs were in the range of 120–7295 ng g⁻¹, with the most abundant contaminant being DBDPE, which is widely used as a substitute for the deca-BDE formulation. DRCs were the least common flame retardants in the Latvian indoor environments, with concentrations ranging 22.4–192 ng g⁻¹. Although the concentrations of specific FRs are known to vary between different countries, the levels and patterns observed in dust samples from Latvia were similar to those reported from Central Europe. Human exposure was evaluated as the estimated daily intake (EDI). The calculated exposure to most of the FRs was several orders of magnitude lower than the available reference dose (RfD) values.

Polychlorinated biphenyls (PCBs) were important industrial chemicals featuring high thermal and chemical stability and low flammability. They were widely used as dielectric and thermal fluid in closed electro-technical applications (transformers, capacitors…) and also in numerous dispersive uses, ranking from auto-copying paper to sealant or coatings. During the 1960s, severe environmental consequences started becoming apparent. The stability of PCBs contributed to their persistence in the environment, their lipophilic character to bio-magnification. Fish-eating species seemed threatened in their existence. In Japan and in Taiwan, thousands of people consumed PCB-contaminated oil. The production of PCBs stopped completely during the 1980s. Usage could continue in closed applications only. In this paper, particular attention is given to two issues: the cleaning of PCB electric transformers and the potential impact of PCB-containing building materials. Other contributions will cover the management and treatment of PCB-contaminated soil, sludge or fly ash. The complete survey is being prepared by request of the Knowledge Center for Engineers and Professionals.