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Is there a similarity between the 2019 and 2022 oil spills that occurred on the coast of Ceará (Northeast Brazil)? An analysis based on forensic environmental geochemistry
2022
de Azevedo, Rufino Neto A. | Bezerra, Kamylla M.M. | Nascimento, Ronaldo F. | Nelson, Robert K. | Reddy, Christopher M. | do Nascimento, Adriana P. | Oliveira, André H.B. | Martins, Laercio L. | Cavalcante, Rivelino M.
The main objective of this study was to investigate the 2019 and 2022 oil spill events that occurred off the coast of the State of Ceará, Northeastern Brazil. To further assess these mysterious oil spills, we investigated whether the oils stranded on the beaches of Ceará in 2019 and 2022 had the same origin, whether their compositional differences were due to weathering processes, and whether the materials from both were natural or industrially processed. We collected oil samples in October 2019 and January 2022, soon after their appearance on the beaches. We applied a forensic environmental geochemistry approach using both one-dimensional and two-dimensional gas chromatography to assess chemical composition. The collected material had characteristics of crude oil and not refined oils. In addition, the 2022 oil samples collected over 130 km of the east coast of Ceará had a similar chemical profile and were thus considered to originate from the same source. However, these oils had distinct biomarker profiles compared to those of the 2019 oils, including resistant terpanes and triaromatic steranes, thus excluding the hypothesis that the oil that reached the coast of Ceará in January 2022 is related to the tragedy that occurred in 2019. From a geochemical perspective, the oil released in 2019 is more thermally mature than that released in 2022, with both having source rocks with distinct types of organic matter and depositional environments. As the coast of Ceará has vast ecological diversity and Marine Protected Areas, the possibility of occasional oil spills in the area causing severe environmental pollution should be investigated from multiple perspectives, including forensic environmental geochemistry.
Afficher plus [+] Moins [-]Interspecies variation in the susceptibility of adult Pacific salmon to toxic urban stormwater runoff
2018
McIntyre, Jenifer K. | Lundin, Jessica I. | Cameron, James R. | Chow, Michelle I. | Davis, Jay W. | Incardona, John P. | Scholz, Nathaniel L.
Adult coho salmon (Oncorhynchus kisutch) prematurely die when they return from the ocean to spawn in urban watersheds throughout northwestern North America. The available evidence suggests the annual mortality events are caused by toxic stormwater runoff. The underlying pathophysiology of the urban spawner mortality syndrome is not known, and it is unclear whether closely related species of Pacific salmon are similarly at risk. The present study co-exposed adult coho and chum (O. keta) salmon to runoff from a high traffic volume urban arterial roadway. The spawners were monitored for the familiar symptoms of the mortality syndrome, including surface swimming, loss of orientation, and loss of equilibrium. Moreover, the hematology of both species was profiled by measuring arterial pH, blood gases, lactate, plasma electrolytes, hematocrit, and glucose. Adult coho developed behavioral symptoms within a few hours of exposure to stormwater. Various measured hematological parameters were significantly altered compared to coho controls, indicating a blood acidosis and ionoregulatory disturbance. By contrast, runoff-exposed chum spawners showed essentially no indications of the mortality syndrome, and measured blood hematological parameters were similar to unexposed chum controls. We conclude that contaminant(s) in urban runoff are the likely cause of the disruption of ion balance and pH in coho but not chum salmon. Among the thousands of chemicals in stormwater, future forensic analyses should focus on the gill or cardiovascular system of coho salmon. Because of their distinctive sensitivity to urban runoff, adult coho remain an important vertebrate indicator species for degraded water quality in freshwater habitats under pressure from human population growth and urbanization.
Afficher plus [+] Moins [-]Forensic assessment of polycyclic aromatic hydrocarbons at the former Sydney Tar Ponds and surrounding environment using fingerprint techniques
2016
MacAskill, N Devin | Walker, Tony R. | Oakes, Ken | Walsh, Margaret
Polycyclic aromatic hydrocarbons (PAHs) were assessed spatially and temporally within and adjacent to a former coking and steel manufacturing facility in Sydney, Nova Scotia, Canada. Concentrations of PAHs were measured in surface soils, marine and estuary sediments prior to and during remediation of the Sydney Tar Ponds (STPs) site which was contaminated by nearly a century of coking and steel production. Previous studies identified PAHs in surficial marine sediments within Sydney Harbour, which were considered to be derived from STP discharges. Numerous PAH fingerprint techniques (diagnostic ratios, principal component analysis, quantitative and qualitative analysis) were applied to soil and sediment samples from the STPs and surrounding area to identify common source apportionment of PAHs. Results indicate coal combustion (from historical residential, commercial and industrial uses) and coal handling (from historic on-site stockpiling and current coal transfer and shipment facilities) are likely the principal source of PAHs found in urban soils and marine sediments, consistent with current and historical activities near these sites. However, PAH fingerprints associated with STP sediments correlated poorly with those of urban soils and marine sediments, but were similar to coal tar, historically consistent with by-products produced by the former coking operations. This study suggests PAH contamination of Sydney Harbour sediments and urban soils is largely unrelated to historic coking operations or recent remediation of the STPs site, but rather a legacy of extensive use of coal for a variety of activities.
Afficher plus [+] Moins [-]An SPE LC–MS/MS method for the analysis of human and veterinary chemical markers within surface waters: An environmental forensics application
2013
Fenech, Cecilia | Nolan, Kieran | Rock, Luc | Morrissey, Anne
In this study, the use of co-occurring discriminators of sewage and manure was assessed as a potential way to disentangle sewage and manure sources. A suite of human and veterinary derived chemical markers, which includes pharmaceuticals and compound such as food additives, has been identified for this purpose. The suite was selected in such a manner as to provide additional source characterisation, e.g. differentiating raw versus treated sewage inputs. An SPE–LC–MS/MS method was developed and validated for the determined suite of chemical markers with a detection limit of up to 50 pg L−1. This represents one of the lowest limits of detection for pharmaceuticals reported in literature. To illustrate the suitability of the proposed method to differentiate sewage and manure inputs to surface water bodies, results from surface water samples collected at monitoring sites corresponding to specific land use types within Ireland are discussed.
Afficher plus [+] Moins [-]Concentrations and source identification of PAHs, alkyl-PAHs and other organic contaminants in sediments from a contaminated harbor in the Laurentian Great Lakes
2021
Buell, Mary-Claire | Johannessen, Cassandra | Drouillard, Ken | Metcalfe, Chris
As a result of historical industrial activity, the sediments in the inner harbor of Owen Sound Bay in the northeastern part of Lake Huron in Ontario, Canada are contaminated with organic compounds. The present study showed that the concentrations of Ʃ PAH₁₆₋EPA in all sediments in the inner harbor were above the sediment quality guidelines for the province of Ontario, Canada, with mean Ʃ PAH₁₆₋EPA concentrations at the most contaminated site of 46,000 μg/kg dry weight. The concentrations of polychlorinated biphenyls, brominated diphenyl ethers, and organochlorine compounds were all below sediment quality guidelines. The patterns of PAH and alkyl-PAH compounds in sediment cores indicated that contamination is from mixed sources, with a strong indication of pyrogenic contamination from industries that used to operate in the area, including a coal gasification plant. Other areas of the bay are impacted by petrogenic contamination, potentially from spills of fuel. The even distribution of PAH and alkyl-PAH compounds throughout core profiles at depths up to 25 cm indicates that this is a dynamic system and contaminated sediments are not being covered by deposition of less contaminated sediments. This study illustrates the value of determining the patterns of both PAH and alkyl-PAH compounds in sediments for regulatory purposes and also for forensic source tracking.
Afficher plus [+] Moins [-]PAH source differentiation between historical MGP and significant urban influences for sediments in San Francisco Bay
2021
Jordan, Randy E. | Cejas, Mark J. | Costa, Helder J. | Sauer, Theodor C. | McWilliams, Laura S.
A forensic source evaluation of polycyclic aromatic hydrocarbons (PAHs) in nearshore sediments in San Francisco Bay examined total PAH greater than ambient concentrations in sediments, and potential pyrogenic source relationships with respect to PAH compounds typically associated with point and nonpoint pyrogenic source types, including PAHs potentially associated with historical manufactured gas plant (MGP) operations. Diagnostic source ratio analysis was employed for determination of potential PAH source relationships. A two-model approach indicated distinct potential source signatures, as identified from the distributions of higher PAH concentrations in some sediments. Source characterization was aided by Polytopic Vector Analysis (PVA) and data visualization with t-Distributed Stochastic Neighbor Embedding (t-SNE). Two signatures exhibited pyrogenic character likely consistent with historical MGP sources, and one signature was related to creosote. A distinct and significant source of PAHs to the investigation area sediment consisted of ubiquitous nonpoint and potential unidentified point sources is termed “urban influence”.
Afficher plus [+] Moins [-]Is this your glitter? An overlooked but potentially environmentally-valuable microplastic
2019
Tagg, Alexander S. | Ivar do Sul, Juliana A.
As microplastic pollution evolved to a well-established research field, microplastic scientists started to explore new avenues in the field. Yet, while a multitude of different types of microplastics (microbeads, fibres, fragments) have been well-documented in microplastic literature, our analysis of this literature shows that glitter particles have been overlooked by the field. However, due to the presence of glitter-based research in forensic science, we explore the idea that glitter may have the potential to act as “flag items” - or markers – of a likely source, due to the often complex and individual composition of glitter particles compared to traditional microplastics, such as microbeads. As such, this article demonstrates glitter has insofar been overlooked as a microplastic particle, and demonstrates that glitter may have an important role in explaining microplastic pollution dynamics from source to sink.
Afficher plus [+] Moins [-]Macondo oil in deep-sea sediments: Part 2 — Distribution and distinction from background and natural oil seeps
2016
Stout, Scott A. | Payne, James R. | Ricker, Robert W. | Baker, Gregory | Lewis, Christopher
Following the Deepwater Horizon oil spill, the spilled Macondo oil was severely weathered during its transport within the deep-sea plume as discrete particles, which were subsequently deposited on the seafloor. The Macondo oil deposited in deep-sea sediments was distinguished from ambient (background) hydrocarbons and naturally-seeped and genetically-similar oils in the Mississippi Canyon region using a forensic method based upon a systematic, multi-year study of 724 deep-sea sediment cores collected in late 2010 and 2011. The method relied upon: (1) chemical fingerprinting of the distinct features of the wax-rich, severely-weathered Macondo oil; (2) hydrocarbon concentrations, considering a core's proximity to the Macondo well or to known or apparent natural oil seeps, and also vertically within a core; and (3) results from proximal cores and flocculent material from core supernatants and slurp gun filters. The results presented herein establish the geographic extent of “fingerprintable” Macondo oil recognized on the seafloor in 2010/2011.
Afficher plus [+] Moins [-]Forensic investigation of aliphatic hydrocarbons in the sediments from selected mangrove ecosystems in the west coast of Peninsular Malaysia
2015
Vaezzadeh, Vahab | Zakaria, Mohamad Pauzi | Shau-Hwai, Aileen Tan | Ibrahim, Zelina Zaiton | Mustafa, Shuhaimi | Abootalebi-Jahromi, Fatemeh | Masood, Najat | Magam, Sami Mohsen | Alkhadher, Sadeq Abdullah Abdo
Peninsular Malaysia has gone through fast development during recent decades resulting in the release of large amounts of petroleum and its products into the environment. Aliphatic hydrocarbons are one of the major components of petroleum. Surface sediment samples were collected from five rivers along the west coast of Peninsular Malaysia and analyzed for aliphatic hydrocarbons. The total concentrations of C10 to C36 n-alkanes ranged from 27,945 to 254,463ng·g−1dry weight (dw). Evaluation of various n-alkane indices such as carbon preference index (CPI; 0.35 to 3.10) and average chain length (ACL; 26.74 to 29.23) of C25 to C33 n-alkanes indicated a predominance of petrogenic source n-alkanes in the lower parts of the Rivers, while biogenic origin n-alkanes from vascular plants are more predominant in the upper parts, especially in less polluted areas. Petrogenic sources of n-alkanes are predominantly heavy and degraded oil versus fresh oil inputs.
Afficher plus [+] Moins [-]Assessment of photochemical processes in marine oil spill fingerprinting
2014
Radović, Jagoš R. | Aeppli, Christoph | Nelson, Robert K. | Jiménez, Nuria | Reddy, Christopher M. | Bayona, Josep M. | Albaigés, Joan
Understanding weathering processes plays a critical role in oil spill forensics, which is based on the comparison of the distributions of selected compounds assumed to be recalcitrant and/or have consistent weathering transformations. Yet, these assumptions are based on limited laboratory and oil-spill studies. With access to additional sites that have been oiled by different types of oils and exposures, there is a great opportunity to expand on our knowledge about these transformations. Here, we demonstrate the effects of photooxidation on the overall composition of spilled oils caused by natural and simulated sunlight, and particularly on the often used polycyclic aromatic hydrocarbons (PAHs) and the biomarker triaromatic steranes (TAS). Both laboratory and field data from oil released from the Macondo well oil following the Deepwater Horizon disaster (2010), and heavy fuel-oil from the Prestige tanker spill (2002) have been obtained to improve the data interpretation of the typical fingerprinting methodology.
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