Reuse of sewage sludge is a general trend and land application is an essential way to reuse sludge. The outbreak of coronavirus disease has raised concerns about human pathogens and their serious threat to public health. The risk of pathogenic bacterial contamination from land application of municipal sludge has not been well assessed. The purpose of this study was to investigate the presence of pathogenic bacteria in municipal sewage sludge and to examine the survival potential of certain multidrug-resistant enteroaggregative Escherichia coli (EAEC) strain isolated from sewage sludge during heat treatment. The sewage sludge produced in the two wastewater treatment plants contained pathogenic bacteria such as pathogenic E. coli, Shigella flexneri, and Citrobacter freundii. The environmental strain of EAEC isolated from the sludge was resistant to eight types of antibiotics. It could also enter the dormant state after 4.5 h of treatment at 55 °C and regrow at 37 °C, while maintaining its antibiotic resistance. Our results indicate that the dormancy of EAEC might be why it is heat-resistant and could not be killed completely during the sludge heat treatment process. Owing to the regrowth of the dormant pathogenic bacteria, it is risky to apply the sludge to land even if the sludge is heat-treated, and there is also a risk of spreading antibiotic resistance.

Exploring effective uses of waste concrete powder (WCP), produced from recycling of construction & demolition waste is beneficial to the environment and sustainable development. In this study, WCP was first treated thermally to enhance the ability to remove Pb (II) from aqueous solutions. The experimental results revealed that the thermal treatment could enhance adsorption capacity due to modification of calcium bonding and pore structure of WCP. Preparation parameters such as temperature, particle size, and water-cement ratio were investigated to obtain the optimal operational conditions. Batch adsorption experiments were performed to explore influence factors of pH (1.00–6.00), ionic strength (0.05–2 mol/L), dosage (2–50 g/L), and temperature (25–45 °C). The pseudo-second-order kinetics model could adequately describe the adsorption process, and the Langmuir model was capable to predict the isotherm data well in the low concentration region (C₀ < 500 mg/L). The maximum uptake capacity for Pb (II) calculated by Langmuir model at 25, 35 and 45 °C were 46.02, 38.58 and 30.01 mg/g respectively, and the removal rate of Pb (II) was 92.96% at a dosage of 50 g/L (C₀ = 1000 mg/L). Precipitation, ion exchange, and surface complexation were identified to be the main mechanisms of Pb (II) adsorption through microscopic investigation by SEM-EDX, XRD, FTIR, XPS, and BET inspections. The study confirms that the WCP after thermal modification, can be selected as a promising adsorbent for the high performance and eco-friendliness.

Antibiotics are commonly used in livestock and poultry breeding along with organic arsenic. Through long-term accumulation, they can enter into the surrounding soil through various pathways and contaminate the soil. In this paper, tetracycline antibiotics (TCs) and roxarsone (ROX) contaminated soil were used as the representatives of the two kinds of veterinary drugs contaminated soil, respectively, to study the thermal desorption behavior and arsenic stabilization process. Different parameters like heating temperatures, heat duration, stabilizer type and dosage were optimized for effective removal of TCs and ROX. Furthermore, TCs and ROX removal path and ROX stabilization mechanism were explored. Results of the study showed that over 98% of tetracycline antibiotics and roxarsone were effectively removed at 300 °C for 60 min. The heat treatment process of TCs contaminated soil was controlled by the first-order kinetics. Based on the detection of degradation products and thermogravimetric analysis, the possible thermal degradation path of TCs and ROX was proposed. Addition of FeSO₄.7H₂O (10% by weight) as stabilizer during the heat treatment process yielded 96.7% stabilization rate. Through the analysis of arsenic fractions, valence and the characterization of soil samples collected after the heat treatment, mechanism of arsenic stabilization in ROX was explored. The results show that thermal treatment combined with chemical stabilization technology can not only degrade TCs and ROX efficiently and completely, but also convert organic arsenic into inorganic state, which is conducive to better stabilization, and finally achieve effective and safe remediation of this kind of contaminated soil.

Sawdust wastes were used as precursors to prepare adsorbents by combustion and pyrolysis for experimental and mechanism studies and determine the potential of biomass extracted from agro-industrial residues for Pb-polluted soil remediation. Pot experiments were conducted on contaminated soils near Pb–Zn mining with sawdust ash (SA) and sawdust biochar (SB) in different proportions and dosage ratios. Studies have indicated that the application of biomass materials can enhance the adsorption, complexation and precipitation of Pb cations in soil and reduce the mobility of Pb. The concentrations of SPLP-Pb and DTPA-extractable Pb in amended soils were the lowest under 1% 1:2 and 5% 1:1 treatment, respectively. Results of fraction extraction and XANES analysis showed that the materials change the main forms of Pb in soil. Moreover, the binding behavior of Pb with organic matter increases the proportion of Pb (Ac)₂, leading to the transformation of high toxicity Pb-compounds into precipitates and complexes. The remediation methods of 2% 1:2 and 5% 1:2 were better than those of other methods in stabilizing Pb in soil. This study indicated that heat-treated sawdust can be used for Pb-polluted soil remediation, which is a type of environmental remediation measure with considerable ecological potential.

The microparticle content of 37 common facial and body scrubs commercially available in the United Arab Emirates was analyzed. The chemical composition, ash content, physical characteristics, loading, particle size and shape of the microparticles were determined. Only 11 out of 37 products were found to have microplastic content. Many of the remaining products exhibited microparticles composed of microcrystalline cellulose and crushed walnut shells. Differential scanning calorimetry showed that microplastic products had softening points as low as 84 °C. Plastic microbeads of 2 products were found to fuse at 100 °C. The fusion altered the flotation characteristics of the microbeads of one product. Heat treatment of the product at 100 °C in the presence of silica gel led to entrainment of the silica and partial fragmentation of the beads upon cooling. This may be understood as one mechanism of fragmentation of a microplastic with a low softening point in the presence of hard soil particles under temperature cycling.

Sludge dewatering is an important process in municipal wastewater treatment and critically influences the subsequent transportation and disposal. Thermal treatment coupled with other chemical processes has been widely used to improve sludge dewaterability. However, information about the response of sludge extracellular polymeric substances (EPS) to thermal treatment and its role in sludge dewatering is still limited. In this work, the effects of thermal treatment on anaerobic and aerobic sludges were investigated with an emphasis on the colloid properties of released EPS in sludge dewatering process. The results indicate that sludge dewaterability became deteriorated with the increased temperature in the range of 30–170 °C, which was ascribed to the disintegration of sludge flocs and change of EPS characteristics. Disintegrated sludge induced the release of the negatively charged EPS, resulting in the weakened bridging interaction and lower compactness. After thermal treatment, the EPS with a higher average molecular weight and stretched coil configuration retained more water. In addition, difference in dewaterability between anaerobic and aerobic sludges was found to be attributed to their different contents and structures of EPS components. These results provide an insight into thermal-dependent sludge dewatering process and are useful to facilitate water-sludge separation.

This study focuses primarily on the inventory of PCDD/Fs and PBDD/Fs associated with the low-temperature thermal processing of scrap printed circuit boards (PCBs). Twelve 2,3,7,8-substituted PBDD/Fs congeners were found in various sample outputs, with a total content of 60,000ng TEQ/kg at 250°C under air atmosphere. A rapid increase of PBDD/Fs was produced with 160,000ng TEQ/kg, at 275°C—about twice that under the N₂ atmosphere. At 275°C, the total contents of PCDD/Fs were only 170 and 770ng TEQ/kg under an N₂ and air atmospheres respectively. The results reveal that a large contribution of PBDD/Fs emission may be expected from the dismantling or any other thermal processing of PCB scrap. PCDD/Fs, however, are formed and released into the environment in a variety of ways. Additional research is required to look for the causal factors that affect emissions.

Intentional or incidental thermal changes inevitably occur during the lifecycle of plastics. High temperatures accelerate the aging of plastics and promote their fragmentation to microplastics (MPs). However, there is little information available on the release of MPs after fires. In this study, an atomic force microscope combined with nanoscale infrared analysis was used to demonstrate the physicochemical properties of polypropylene (PP) plastics under simulated fire scenarios. Results showed that the chemical composition and relative stiffness of heat-treated plastic surfaces changed, significantly enhancing the generation of MPs under external forces; over (2.1 ± 0.2) × 10⁵ items/kg abundance of MPs released from PP which were burned at 250 °C in air and trampled by a person. The leaching of antimony (Sb) from MPs in different solutions first increased and then decreased with increasing temperature, reaching a maximum at 250 °C. Higher concentrations of humic acid (10 vs 1 mg/L) caused a greater release of Sb. Furthermore, the tap water leachates of PP burned at 250 °C had the greatest effect on the growth and photosynthetic activity of Microcystis aeruginosa. Our results suggest fires as a potential source of MPs and calls for increased focus on burning plastics in future research.

Advanced oxidation processes (AOPs) based on peroxymonosulfate (PMS) activation have attracted increasing attention in recent years for organic pollutants removal. Herein, we put forward a facile method to form cobalt phosphide/carbon composite for PMS activation. Combining impregnation approach with pyrolysis treatment enabled the formation of Co₂P/biochar composites using baker’s yeast and Co²⁺ as precursors. The as-synthesized products exhibited excellent catalytic activity for sulfamethoxazole (SMX) degradation over the pH range 3.0–9.0 b y activating PMS. For example, 100% of SMX (20 mg L⁻¹) removal was achieved in 20 min with catalyst dosage of 0.4 g L⁻¹ and PMS loading of 0.4 g L⁻¹. Near zero Co²⁺ leaching was observed during catalytic reaction, which remarkably lowered the toxic risk of transition metal ion in water. Meanwhile, the reusability of catalyst could be attained by thermal treatment. SMX degradation intermediates were identified by liquid chromatography-mass spectrometry (LC-MS), which facilitated the proposal of possible SMX degradation pathways. Ecological Structure Activity Relationships (ECOSAR) analysis indicated that SMX degradation intermediates may not pose ecological toxicity to the environment. Further investigation verified that Co₂P/biochar composites could set off PMS activation not only for the degradation of SMX but also for other sulfonamides. In this study, we not only developed a facile method of utilizing environmental-benign biomass for transition metal phosphide/carbon composite formation, but also achieved highly efficient antibiotic elimination by PMS-based AOP.