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Lead and other elements in house dust of Japanese residences – Source of lead and health risks due to metal exposure
2014
Yoshinaga, Jun | Yamasaki, Kumiko | Yonemura, Ayumi | Ishibashi, Yuri | Kaido, Takaya | Mizuno, Kodai | Takagi, Mai | Tanaka, Atsushi
The levels of 25 elements in house dust collected from 100 general Japanese residences were measured. Factor analysis was applied on the multi-element data to explore source of Pb (median concentration 49.1 mg/kg) in house dust. Six factors were extracted and Pb was found to have great loading on the fifth factor with Sb and Sn, suggesting solder (Sn), and plastic and metals (Sb) may be the sources of Pb in the house dust of Japanese residences. No significant loading was found on soil-related factors indicating non-significant contribution of Pb in track-in soil. Seven heavy metals (Cd, Cu, Mo, Pb, Sb, Sn, and Zn) were found in house dust at >10 times more condensed than crustal abundance. Health risk of these elements to children via the ingestion of house dust was estimated based on the comparison with tolerable daily intake and found to be non-significant for most of the elements.
Afficher plus [+] Moins [-]Urban snow indicates pollution originating from road traffic
2014
Kuoppamäki, Kirsi | Setälä, Heikki | Rantalainen, Anna-Lea | Kotze, D Johan
Traffic is a major source of pollutants in cities. In this well-replicated study we analysed a broad array of contaminants in snowpacks along roads of different traffic intensities. The majority of pollutants showed a similar pattern with respect to traffic intensity: pH and conductivity as well as concentrations of PAHs, total suspended solids, phosphorus and most heavy metals were higher next to high intensity roads compared to low intensity roads. These pollutant levels also decreased considerably up to 5 m distance from the roads. Furthermore, apart from nitrogen, these variables increased in concentration from control sites in urban forest patches to road bank sites next to roads of low, intermediate and high traffic intensities. The deposition pattern of various traffic-derived pollutants – whether gaseous or particle-bound – was the same. Such information can be useful for the purposes of managing pollutants in urban areas.
Afficher plus [+] Moins [-]Magnetic susceptibility of road deposited sediments at a national scale – Relation to population size and urban pollution
2014
Jordanova, Diana | Jordanova, Neli | Petrov, Petar
Magnetic properties of road dusts from 26 urban sites in Bulgaria are studied. Temporal variations of magnetic susceptibility (χ) during eighteen months monitoring account for approximately 1/3rd of the mean annual values. Analysis of heavy metal contents and magnetic parameters for the fraction d < 63 μm reveal significant correlations (p < 0.05) between χ and Fe, Mn and PLI index. The highest negative correlation (R2 = −0.84) is observed between the ratio ARM/χ and Pb content. It suggests that Pb is related to brake/tyre wear emissions, releasing larger particles and higher Pb during slow driving – braking. Bulk χ values of road dusts per city show significant correlation with population size and mean annual NO2 concentration on a log-normal scale. The results demonstrate the applicability of magnetic measurements of road dusts for estimation of mean NO2 levels at high spatial density, which is important for pollution modelling and health risk assessment.
Afficher plus [+] Moins [-]Spatial distribution of PAH concentrations and stable isotope signatures (δ13C, δ15N) in mosses from three European areas – Characterization by multivariate analysis
2014
Foan, L. | Leblond, S. | Thöni, L. | Raynaud, C. | Santamaría, J.M. | Sebilo, M. | Simon, V.
Polycyclic aromatic hydrocarbon (PAH) concentrations and N, C stable isotope signatures were determined in mosses Hypnum cupressiforme Hedw. from 61 sites of 3 European regions: Île-de-France (France); Navarra (Spain); the Swiss Plateau and Basel area (Switzerland). Total PAH concentrations of 100–700 ng g−1, as well as δ13C values of −32 to −29‰ and δ15N values of −11 to −3‰ were measured. Pearson correlation tests revealed opposite trends between high molecular weight PAH (4–6 aromatic rings) content and δ13C values. Partial Least Square regressions explained the very significant correlations (r > 0.91, p < 0.001) between high molecular weight PAH concentrations by local urban land use (<10 km) and environmental factors such as elevation and pluviometry. Finally, specific correlations between heavy metal and PAH concentrations were attributed to industrial emissions in Switzerland and road traffic emissions in Spain.
Afficher plus [+] Moins [-]Characterization of fish hold effluent discharged from commercial fishing vessels into harbor waters
2014
Albert, Ryan J. | McLaughlin, Christine | Falatko, Debra
Fish hold effluent and the effluent produced from the cleaning of fish holds may contain organic material resulting from the degradation of seafood and cleaning products (e.g., soaps and detergents). This effluent is often discharged by vessels into near shore waters and, therefore, could have the potential to contribute to water pollution in bays and estuaries. We characterized effluent from commercial fishing vessels with holds containing refrigerated seawater, ice slurry, or chipped ice. Concentrations of trace heavy metals, wet chemistry parameters, and nutrients in effluent were compared to screening benchmarks to determine if there is a reasonable potential for effluent discharge to contribute to nonattainment of water quality standards. Most analytes (67%) exceeded their benchmark concentration and, therefore, may have the potential to pose risk to human health or the environment if discharges are in significant quantities or there are many vessels discharging in the same areas.
Afficher plus [+] Moins [-]The application of histo-cytopathological biomarkers in the mud crab Scylla serrata (Forskal) to assess heavy metal toxicity in Pulicat Lake, Chennai
2014
Arockia Vasanthi, Lourduraj | Muruganandam, Azhagu | Revathi, Peranandam | Baskar, Balakrishnan | Jayapriyan, Kodhilmozhian | Baburajendran, Ramaswamy | Munuswamy, Natesan
The concentrations of heavy metals and their associated structural deformities in the gills, muscles and hepatopancreas of Scylla serrata from Pulicat Lake were determined and compared with crabs live along Kovalam coast. The concentrations of metals were high in the hepatopancreas and gills of crab from Pulicat Lake, whereas, low in crab from the Kovalam coast. Data were visualized using a principal component analysis (PCA). Significant differences were found for all variables at the plot scale; however, the overall variation was relatively low for muscle tissues in both stations. The structural deformities observed in the gills, hepatopancreas and muscle was due to metal toxicity, and the degree of damage was correlated with the elevated metal concentration. The results showed significant metal accumulation and histo-cytological lesions in the crabs from Pulicat Lake. The results suggest that these biomarkers are useful for assessing the impact of metal pollution in the coastal environments.
Afficher plus [+] Moins [-]Metallothioneins pattern during ontogeny of coastal dolphin, Pontoporia blainvillei, from Argentina
2014
Polizzi, P.S. | Romero, M.B. | Chiodi Boudet, L.N. | Das, K. | Denuncio, P.E. | Rodríguez, D.H. | Gerpe, M.S.
Metallothioneins are signals of metal exposure and widely used in biomonitoring. Franciscana dolphin is an endemic cetacean from the Southwestern Atlantic Ocean, classified as Vulnerable A3d by the IUCN. Metallothionein, copper and zinc in Franciscana were assessed in two geographic groups; one inhabits La Plata River estuary, anthropogenically impacted, and the other inhabits marine coastal ecosystems, with negligible pollution. Despite the environment, hepatic and renal MT concentrations were similar, but there was a declining trend from early to later developmental stages. Metallothionein K/L, Cu and Zn levels corresponded to normal reported ranges. MT was not related with Cd. Fetal concentrations were higher than its mother. These results and the health status of dolphins are suggesting that MT correspond to physiological ranges for the species, and they are closely to homeostasis of Zn and Cu, according to its ontogenetic changes. The information constitutes the first MT information on Franciscana dolphin and can be considered as baseline for the species conservation.
Afficher plus [+] Moins [-]Bioaccumulation of heavy metals in commercially important marine fishes from Mumbai Harbor, India
2014
Velusamy, A. | Satheesh Kumar, P. | Ram, Anirudh | Chinnadurai, S.
Seventeen commercially important marine fish species were caught in Mumbai Harbor using a trawl net and evaluated using Atomic Absorption Spectroscopy and ICP-OES. It was found that certain species of fish contained lower levels of all metals tested. J. elongatus and C. dussumieri had the highest levels of all 8 metals tested. The heavy metal concentrations were significantly varied within and between the studied fishes (p<0.05). However, a significant correlation among heavy metals was observed. This investigation indicated that various levels of heavy metals exist in the fish species sampled, but those concentrations are within the maximum residual levels recommended by the European Union and FAO/WHO. Therefore, fish caught in Mumbai Harbor can be considered safe for human consumption.
Afficher plus [+] Moins [-]Total petroleum hydrocarbons and heavy metals in the surface sediments of Bohai Bay, China: Long-term variations in pollution status and adverse biological risk
2014
Zhou, Ran | Qin, Xuebo | Peng, Shitao | Deng, Shihuai
Surface sediments collected from 2001 to 2011 were analyzed for total petroleum hydrocarbons (TPH) and five heavy metals. The sediment concentration ranges of TPH, Zn, Cu, Pb, Cd and Hg were 6.3–535μg/g, 58–332μg/g, 7.2–63μg/g, 4.3–138μg/g, 0–0.98μg/g, and 0.10–0.68μg/g, respectively. These results met the highest marine sediment quality standards in China, indicating that the sediment was fairly clean. However, based on the effects range-median (ERM) quotient method, the calculated values for all of the sampling sites were higher than 0.10, suggesting that there was a potential adverse biological risk in Bohai Bay. According to the calculated results, the biological risk decreased from 2001 to 2007 and increased afterwards. High-risk sites were mainly distributed along the coast. This study suggests that anthropogenic influences might be responsible for the potential risk of adverse biological effects from TPH and heavy metals in Bohai Bay.
Afficher plus [+] Moins [-]The distribution of heavy metals including Pb, Cd and Cr in Kendari Bay surficial sediments
2014
Armid, Alrum | Shinjo, Ryuichi | Zaeni, Ahmad | Sani, Asrul | Ruslan, Ruslan
The surficial coastal sediments in Kendari Bay are sampled in the field to determine the concentration and pollution level of three heavy metals (Pb, Cd and Cr). Twenty-five sampling points ranging from the inner (Wanggu River) to the outer area of the bay have been chosen. The physicochemical properties, such as temperature, pH, salinity and TDS of the overlying water, as well as the sediment type and TOC of the surficial sediments, are also measured. The total concentrations of the Pb, Cd and Cr in the sediment samples are quantified using inductively-coupled plasma mass spectrometry (ICP-MS). The concentrations of the heavy metals (Pb, Cd and Cr) ranged from 0.84 to 17.02μg/g, 0.02 to 0.17μg/g and 1.92 to 40.11μg/g (dry weight), respectively, following the Cr>Pb>Cd sequence. To assess the degree of contamination, a geoaccumulation index (Igeo) is measured. Kendari Bay is not a contaminated area regarding Pb, Cd and Cr.
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